23251-44-7Relevant academic research and scientific papers
Electrochemical carboxylation of terminal alkynes catalyzed by nickel complexes: unusual regioselectivity
Dunach, Elisabet,Perichon, Jacques
, p. 239 - 246 (1988)
The electrochemical reduction of the nickel(II) complex Ni(bipy)3(BF4)2 yields an active catalyst for the regioselective functionalization of the 2-position of terminal alkynes with carbon dioxide.A series of α-substituted acrylic acids have been obtained with selectivities of 65-90percent and fair overall yields.
