233262-34-5Relevant academic research and scientific papers
Regiochemistry of the reaction of 2-acylcyclohexanones with trimethyl orthoformate: A convenient one-pot method to obtain 7,7-dimethoxy alkanoate methyl esters
Martins, Marcos A. P.,Bastos, Giovani P.,Sinhorin, Adilson P.,Flores, Alex F. C.,Bonacorso, Helio G.,Zanatta, Nilo
, p. 789 - 791 (1999)
The regiochemistry of the reaction of 2-acylcyclohexanones [containing 2-acyl groups, C(O)R, where R = Me, Et, CH2Ph, CF3, Ph and OMe] with trimethyl orthoformate to obtain the corresponding acetal derivative is reported. Compounds w
Diastereocontrol in the synthesis of models of rings C and D of phorbol: Directing effect of an ether substituent on lithium carbenoid mediated cyclopropanation
Drew, Michael G. B.,Harwood, Laurence M.,Macias-Sanchez, Antonio J.,Scott, Richard,Thomas,Uguen, Daniel
, p. 2311 - 2313 (2007/10/03)
The diastereocomplementarity of halo- and alkylcarbenes (paths a and b, respectively) was shown in the cyclopropanation reaction of 1. The conversion of 1 into 7,7-dimethylbicyclo[4.1.0]heptan-1,2-diols (±)-2 and (±)-3 represents an important transformati
