362480-55-5

Basic information

• Product Name: 3-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohexanecarboxylic acid methyl ester
• Synonyms: 3-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohexanecarboxylic acid methyl ester
• CAS NO: 362480-55-5
• Molecular Weight: 286.444
• Mol File: 362480-55-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohexanecarboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohexanecarboxylic acid methyl ester(362480-55-5)
• EPA Substance Registry System: 3-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohexanecarboxylic acid methyl ester(362480-55-5)

Safety Data

• Hazardous Substances Data: 362480-55-5(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 362480-54-4 3-hydroxy-2-oxo-cyclohexanecarboxylic acid methyl ester 
• 233262-34-5 2,2-dimethoxy-cyclohexanecarboxylic acid methyl ester 
• 41302-34-5 2-(methoxycarbonyl)cyclohexanone 
• 25662-41-3 Methyl-2-methoxy-2-cyclohexen-1-carboxylat 

Downstream Products

• 362480-56-6 1,6-bis-(tert-butyl-dimethyl-silanyloxy)-cyclohexene 
• 74173-08-3 2-(tert-Butyldimethylsilyloxy)-1-cyclohexanon 

Relevant articles and documents

Diastereocontrol in the synthesis of models of rings C and D of phorbol: Directing effect of an ether substituent on lithium carbenoid mediated cyclopropanation

The diastereocomplementarity of halo- and alkylcarbenes (paths a and b, respectively) was shown in the cyclopropanation reaction of 1. The conversion of 1 into 7,7-dimethylbicyclo[4.1.0]heptan-1,2-diols (±)-2 and (±)-3 represents an important transformati