23355-97-7

Basic information

• Product Name: 1-PHENYL-1,2-EPOXYPROPANE
• Synonyms: 1-PHENYL-1,2-EPOXYPROPANE;TRANS-BETA-METHYLSTYRENE7,8-OXIDE;rel-(2R*,3R*)-2-Phenyl-3-methyloxirane;rel-(2R*,3R*)-2α*-Methyl-3β*-phenyloxirane;rel-(2S*,3S*)-2-Methyl-3-phenyloxirane;rel-2β*-Methyl-3α*-phenyloxirane;trans-β-Methylstyrene 7,8-oxide;trans-β-Methylstyrene oxide
• CAS NO: 23355-97-7
• Molecular Formula: C₉H₁₀O
• Molecular Weight: 134.1751
• Mol File: 23355-97-7.mol
• Article Data: 248

Chemical Properties

• Boiling Point: 202.5°Cat760mmHg
• Flash Point: 68.9°C
• Appearance: /
• Density: 1.044g/cm³
• CAS DataBase Reference: 1-PHENYL-1,2-EPOXYPROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-PHENYL-1,2-EPOXYPROPANE(23355-97-7)
• EPA Substance Registry System: 1-PHENYL-1,2-EPOXYPROPANE(23355-97-7)

Safety Data

• Hazardous Substances Data: 23355-97-7(Hazardous Substances Data)

Usage

Color

Colorless

Physical state

Liquid

Common uses

Intermediate in the synthesis of pharmaceuticals and organic compounds, building block in the production of polymers and resins, solvent, formulation of adhesives and coatings

Reactivity

Reactive compound with a high potential for polymerization

Hazardous properties

Flammable, potential for causing skin and eye irritation, must be handled with care.

Upstream product

• 2311-91-3 monoperoxyphthalic acid 
• 873-66-5 1-propenylbenzene 
• 766-90-5 cis-1-phenyl-1-propylene 
• 498-66-8 norbornene 
• 4962-45-2 2-bromo-1-phenyl-propan-1-ol 
• 14252-63-2 erythro-1-chloro-1-phenyl-2-propanol 
• 637-50-3 1-phenylpropene 
• 14222-20-9 1R,2R-N-methylpseudoephedrine 
• 95-20-5 2-methyl-1H-indole 
• 4541-87-1 cis-1-phenylpropene oxide 
• 4773-35-7 1-chloro-1-phenylpropan-2-one 
• 93-55-0 1-phenyl-propan-1-one 
• 7516-59-8 As-(benzyl)triphenylarsonium bromide 
• 75-07-0 acetaldehyde 

Downstream Products

• 106026-96-4 1-(2-ethoxycarbonylethylthio)-1-phenylpropan-2-ol 
• 106026-94-2 1-(2-acetamido-2-methoxycarbonylethylthio)-1-phenylpropan-2-ol 
• 83204-99-3 (2-Bromo-1-methyl-2-phenyl-ethoxy)-trimethyl-silane 
• 83204-99-3 (2-Bromo-1-methyl-2-phenyl-ethoxy)-trimethyl-silane 
• 83205-10-1 (2-Iodo-1-methyl-2-phenyl-ethoxy)-trimethyl-silane 
• 83205-10-1 (2-Iodo-1-methyl-2-phenyl-ethoxy)-trimethyl-silane 
• 79015-39-7 erythro-1-phenyl-1-phenylthiopropan-2-ol 
• 144174-95-8 (S,R;R,S)-6-Hydroxy-3-(N-methylamino)-1,5-diphenylhept-2-en-1-one 
• 7715-10-8 (1RS,2SR)-1-phenyl-2-(methylthio)propanol 
• 126956-59-0 (1RS,2SR)-1-methyl-2-(methylthio)phenethyl alcohol 
• 60212-00-2 threo-1,2-dithiocyanato-1-phenylpropane 
• 62559-36-8 2,3-syn-2-Phenylbutan-1,3-diol 
• 83205-13-4 tert-Butyl-(2-iodo-1-methyl-2-phenyl-ethoxy)-dimethyl-silane 
• 83205-13-4 tert-Butyl-(2-iodo-1-methyl-2-phenyl-ethoxy)-dimethyl-silane 

Relevant articles and documents

Molybdenum(VI) cis-dioxo complexes bearing sugar derived chiral Schiff-base ligands: Synthesis, characterization, and catalytic applications

Molybdenum(VI)-cis-dioxo complexes bearing sugar derived chiral Schiff-base ligands of general formula MoO2(L)(Solv) have been synthesized (with L = N-salicylidene-D-glucosamine; N-salicylidene-1,3,4,6-tetraacetyl-α-D-glucosamine; N-5-chlorosal

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Chiral ansa-bridged η5-cyclopentadienyl molybdenum complexes: Synthesis, structure and application in asymmetric olefin epoxidation

Ansa-bridged η5-cyclopentadienyl carbonyl molybdenum complexes were synthesized with stereogenic centers located in the side chain. An exemplary X-ray crystal structure and the catalytic activity for asymmetric olefin epoxidation are reported. In non-chiral epoxidation the compounds show a good catalytic activity, comparable to activities observed for the related non-chiral complexes of composition CpMo(CO)3X (X = Cl, CH3). For the asymmetric epoxidation of trans-β-methylstyrene the chiral induction is up to ca. 20%. The high ring strain of the ansa-bridged system hampers, unfortunately, its stability under oxidative condition.

Polymer-bound chiral (salen)Mn(III) complex as heterogeneous catalyst in rapid and clean enantioselective epoxidation of unfunctionalised olefins

The application of a new polystyrene-divinylbenzene system containing an optically active (salen)Mn(III) complex in asymmetric epoxidation of unfunctionalised olefins is reported. This system showed a remarkably high reaction speed in the conditions descr

High-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: Heterolytic cleavage of hydroperoxides

The reactions of hydrogen peroxide or tert-butyl hydroperoxide with cyclooctene and norbornene, catalyzed by iron(III) tetrakis(pentafluorophenyl)porphyrin chloride and other electronegatively-substituted porphyrins, produce 60-100% epoxide yields. The ep

Enantioselective, Stereoconvergent Resolution Copolymerization of Racemic cis-Internal Epoxides and Anhydrides

Unprecedented enantioselective resolution copolymerization of racemic cis-internal epoxides and anhydrides was mediated by dinuclear aluminum complexes with multiple chirality, affording optically active polyesters with two contiguous stereogenic centers, and the unreacted substrates in good enantioselectivity. Unexpected stereoconvergence is observed in this resolution copolymerization, where the selectivity factor for the enantioselective formation of copolymer significantly exceeds the kinetic resolution coefficient based on the unreacted epoxide at various conversions. Catalytic activity and copolymer enantioselectivity are strongly influenced by the phenolate ortho-substituents of the ligand set, as well as the axial linker and its chirality. An enantiopure binaphthol-linked bimetallic AlIII complex allows stereoconvergent access to the stereoregular semi-crystalline polyesters and a concomitant kinetic resolution of the epoxide substrates.

Kinetic resolution ofN-aryl β-amino alcoholsviaasymmetric aminations of anilines

An efficient kinetic resolution ofN-aryl β-amino alcohols has been developedviaasymmetricpara-aminations of anilines with azodicarboxylates enabled by chiral phosphoric acid catalysis. Broad substrate scope and high kinetic resolution performances were afforded with this method. Control experiments supported the critical roles of the NH and OH group in these reactions.