233609-15-9

Basic information

• Product Name: Benzoic acid (1S,2R,3R)-3-hydroxy-2,4-dimethyl-1-[2-(2-trimethylsilanyl-ethoxymethoxy)-ethyl]-pent-4-enyl ester
• Synonyms: Benzoic acid (1S,2R,3R)-3-hydroxy-2,4-dimethyl-1-[2-(2-trimethylsilanyl-ethoxymethoxy)-ethyl]-pent-4-enyl ester
• CAS NO: 233609-15-9
• Molecular Weight: 408.61
• Mol File: 233609-15-9.mol

Chemical Properties

• CAS DataBase Reference: Benzoic acid (1S,2R,3R)-3-hydroxy-2,4-dimethyl-1-[2-(2-trimethylsilanyl-ethoxymethoxy)-ethyl]-pent-4-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid (1S,2R,3R)-3-hydroxy-2,4-dimethyl-1-[2-(2-trimethylsilanyl-ethoxymethoxy)-ethyl]-pent-4-enyl ester(233609-15-9)
• EPA Substance Registry System: Benzoic acid (1S,2R,3R)-3-hydroxy-2,4-dimethyl-1-[2-(2-trimethylsilanyl-ethoxymethoxy)-ethyl]-pent-4-enyl ester(233609-15-9)

Safety Data

• Hazardous Substances Data: 233609-15-9(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 233609-14-8 (4S,5S)-5-Hydroxy-2,4-dimethyl-7-(2-trimethylsilanyl-ethoxymethoxy)-hept-1-en-3-one 
• 233609-21-7 [(2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-5-(2-trimethylsilanyl-ethoxymethoxy)-pentyloxymethyl]-benzene 
• 233609-13-7 (4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-2,4-dimethyl-7-(2-trimethylsilanyl-ethoxymethoxy)-hept-1-en-3-ol 
• 233609-22-8 (2R,3S)-3-(tert-Butyl-dimethyl-silanyloxy)-2-methyl-5-(2-trimethylsilanyl-ethoxymethoxy)-pentan-1-ol 
• 233609-23-9 (4S,5S)-2,4-Dimethyl-7-(2-trimethylsilanyl-ethoxymethoxy)-hept-1-ene-3,5-diol 
• 233609-20-6 (3S,4R)-5-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-pentan-1-ol 
• 135708-75-7 [1-((R)-2-Benzyloxy-1-methyl-ethyl)-but-3-enyloxy]-tert-butyl-dimethyl-silane 
• 89046-67-3 (5R)-6-benzyloxy-5-methyl-4-hydroxyhex-1-ene 

Downstream Products

• 233609-16-0 C₂₃H₂₆O₅ 
• 233609-24-0 C₂₉H₄₀O₆Si 

Relevant articles and documents

Synthetic studies toward ansatrienines: Application of the Evans- Tishchenko reaction to chiral enones

Practical syntheses of the C9-C14 sterotriade 5 and the C1-C8 polyene unit 6 in ansatrienine A (mycotriene) (1a), and other ansamycin antibiotics is described. A key step for controlling the configuration of the stereogenic center at C13 involves the stereoselective reduction of enone 10 using the Evans-Tishchenko reaction.