236121-29-2

Upstream product

• 13884-92-9 phenylthiomethyl triphenylphosphonium chloride 
• 100-52-7 benzaldehyde 
• 236121-24-7 (E)-2-ethoxy-1,1,1-trifluoro-3-(phenylthio)prop-2-ene 

Downstream Products

• 236121-42-9 (Z)-1,1,1-trifluoro-4-phenyl-3-(phenylthio)but-3-en-2-one 
• 236121-60-1 (Z)-2,2-diethoxy-1,1,1-trifluoro-4-phenyl-3-(phenylthio)but-3-ene 

Relevant academic research and scientific papers

Novel perfluoroacyl olefinations of aldehydes using β-thio-substituted perfluoroalkyl enol ethers

α-(Methylthio)- or α-(phenylthio)-substituted perfluoroacylolefinations of nonenolizable aldehydes using the β-lithio-β- thio-perfluoroalkyl enol ethers 1-4 stereoselectively proceeded to give (Z)- α,β-unsaturated perfluoroalkyl ketones 9a-e, 10a-c, 11a-c, and 12a. The α- (thio)-α,β-unsaturated trifluoromethyl ketones were easily converted to 3- (thio)-2-(trifluoromethyl)-1,3-butadienes 21a-c and 22a,b in moderate to high yields (41-85%).