23660-12-0Relevant academic research and scientific papers
Total synthesis of oidiodendrolides and related norditerpene dilactones from a common precursor: Metabolites CJ-14,445, LL-Z1271γ, oidiolactones A, B, C, and D, and nagilactone F
Hanessian, Stephen,Boyer, Nicolas,Reddy, Gone Jayapal,Deschenes-Simard, Benoit
, p. 4640 - 4643 (2009)
An efficient, high-yielding strategy has been developed for the asymmetric total synthesis of seven norditerpenoid dilactones known for their diverse biological properties. The three key steps employed to obtain a tricyclic lactone intermediate involved a
An Efficient Synthesis of the Antifungal Dilactone LL-Z1271α and of other Biologically Active Compounds
Barrero, Alejandro F.,Sanchez, Juan F.,Elmerabet, Jamal
, p. 5251 - 5254 (1995)
The syntheses of the terpenoid antifungal LL-Z1271α and other related compounds were achieved starting from the communic acids.The synthetic approach includes a mercuriation-demercuriation reaction of a γ,δ-unsaturated methyl ester in the presence of O2, giving rise to a lactone ring.
Enantiospecific syntheses of the potent bioactives nagilactone F and the mould metabolite LL-Z1271α an evaluation of their allelopathic potential
Barrero, Alejandro F.,Sanchez, Juan F.,Elmerabet, Jamal,Jimenez-Gonzalez, David,Macias, Francisco A.,Simonet, Ana M.
, p. 7289 - 7304 (2007/10/03)
Improved syntheses are described for nagilactone F and the antibiotic LL-Z1271α, two of the most potent bioactive members of the podolactone family. The allelopathic potential of some members of this podolactone series has been evaluated, with the result
