23679-20-1

Basic information

• Product Name: DIALLYLPHOSPHITE
• Synonyms: DIALLYLPHOSPHITE
• CAS NO: 23679-20-1
• Molecular Formula: C₆H₁₁O₃P
• Molecular Weight: 162.12
• Mol File: 23679-20-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• Density: 1.0800
• CAS DataBase Reference: DIALLYLPHOSPHITE(CAS DataBase Reference)
• NIST Chemistry Reference: DIALLYLPHOSPHITE(23679-20-1)
• EPA Substance Registry System: DIALLYLPHOSPHITE(23679-20-1)

Safety Data

• Hazard Codes: 3:
• Safety Statements: x. See also ALLYL COMPOUNDS." target="_blank">A poison. May explode during distillation. When heated to decomposition it emits t
• Hazardous Substances Data: 23679-20-1(Hazardous Substances Data)

Upstream product

• 7647-01-0 hydrogenchloride 
• 102-84-1 triallyl phosphite 
• 3426-89-9 phenyl phosphorodichloridite 
• 107-18-6 allyl alcohol 

Downstream Products

• 16383-57-6 bis(prop-2-en-1-yl)chlorophosphonate 
• 109734-90-9 3-(bis-allyloxy-phosphoryl)-3-phenyl-propionic acid ethyl ester 
• 556-56-9 allyl iodid 
• 3479-30-9 diallyl allylphosphonate 

Relevant articles and documents

Convenient and efficient approach to di- and trideoxyribonucleotide N3′→P5′ phosphoramidates

Arbuzov reaction of phenyl phosphorodichloridite with an equivalent of allyl alcohol and tert-butyl alcohol produced phenyl allyl H-phosphonate and the subsequent ester-exchange with various nucleosides produced nucleoside allyl H-phosphonates. Antherton-Todd reaction of the nucleoside allyl H-phosphonates with 3′-amino-3′-deoxythymidine yielded dideoxyribonucleotide N3′→P5′ phosphoramidates, and the repetition of this procedure provided trideoxyribonucleotide N3′→P5′ phosphoramidates. The method can be used for the synthesis of oligodeoxyribonucleotide N3′→P5′ phosphoramidates without any protection for all nucleosides. Georg Thieme Verlag Stuttgart.