237429-41-3Relevant academic research and scientific papers
Boronated thiophenols: A preparation of 4-mercaptophenylboronic acid and derivatives
Brikh, Abdelghani,Morin, Christophe
, p. 82 - 86 (2007/10/03)
4-Mercaptophenylboronic acid derivatives were prepared by a metallation/boration sequence from S-protected 4-bromothiophenols; the t-butyldimethylsilylthioether was found suitable to allow subsequent regeneration of the mercapto group after boration. The parent compound, 4-mercaptophenylboronic acid, could thus be obtained and was subsequently S-alkylated; 4-boronophenylthioacetic acid was prepared without the need to protect the boronic acid group.
