23780-79-2Relevant academic research and scientific papers
Photochemical Conversion of 2-Thioxo-1,3-dithioles into Tetrathiafulvalenes
Tsujimoto, Kazuo,Okeda, Yukihiro,Ohashi, Mamoru
, p. 1803 - 1804 (2007/10/02)
Photochemical reactions of 4,5-diphenyl-2-thioxo-1,3-dithiole in the presence of an electron donor produce tetraphenyltetrathiafulvalene.
INSERTION OF 1,3-DITHIOLIUM CARBENES INTO N-H BOND OF AMIDES AND IMIDES
Buza, Daniela,Gradowska, Wanda
, p. 1059 - 1069 (2007/10/02)
It was found that 1,3-dithiolium carbenes (4a-d) generated from 2-methoxy-1,3-dithioles (1a-d) were inserted into N-H bond of N-methylbenzamide, acetanilide and succinimide to form N-(1,3-dithiol-2-yl)amides (imides) 8-10, respectively.It was shown that N
CLEAVAGE OF 2-METHOXY-1,3-DITHIOLES BY ACIDS
Buza, Daniela,Gradowska, Wanda
, p. 775 - 782 (2007/10/02)
The reaction of 2-methoxy-1,3-dithioles (1) with acids, yielding 1,3-dithiolium salts (2) or 2,2'-bi(1,3-dithiolylidenes) (3) or both, was studied.It was found that the direction of this reaction was determined by the strength and the proportion of the ac
REACTIONS OF 1,3-DITHIOLIUM CARBENES IN SITU WITH AROMATIC ALDEHYDES
Buza, Daniela,Gradowska, Wanda
, p. 717 - 729 (2007/10/02)
It was found that 1,3-dithiolium carbenes (3) generated from various 1,3-dithiole derivatives reacted with aromatic aldehydes to form 2-benzoyl-2,2'-(1',3'-dithiolyl)-1,3-dithioles (6).The proposed mechanism of reaction has been discussed.
Organic Metals: a New Synthetic Route to Tetrathiafulvalenes
Coustumer, Gerard Le,Mollier, Yves
, p. 38 - 39 (2007/10/02)
We report here a new synthetic route to tetrathiafulvalenes in asimple one-step synthesis from 2-thioxo-1,3-dithioles.
