23853-68-1

Basic information

• Product Name: 1,2,3,4-Tetrahydro-2-(phenylthio)naphthalene
• Synonyms: 1,2,3,4-Tetrahydro-2-(phenylthio)naphthalene
• CAS NO: 23853-68-1
• Molecular Formula: C₁₆H₁₆S
• Molecular Weight: 240.36
• Mol File: 23853-68-1.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,2,3,4-Tetrahydro-2-(phenylthio)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,4-Tetrahydro-2-(phenylthio)naphthalene(23853-68-1)
• EPA Substance Registry System: 1,2,3,4-Tetrahydro-2-(phenylthio)naphthalene(23853-68-1)

Safety Data

• Hazardous Substances Data: 23853-68-1(Hazardous Substances Data)

Upstream product

• 7664-93-9 sulfuric acid 
• 612-17-9 1,4-dihydronaphthalene 
• 64-19-7 acetic acid 
• 108-98-5 thiophenol 
• 768-56-9 4-Phenylbut-1-ene 
• 14204-27-4 N-phenylthiophthalimide 
• 93242-22-9 4-Phenyl-1-phenylsulfanyl-butan-2-ol 
• 447-53-0 1,2-Dihydronaphthalene 

Relevant articles and documents

FeCl3-Catalyzed Regio-Divergent Carbosulfenylation of Unactivated Alkenes: Construction of a Medium-Sized Ring

A FeCl3-catalyzed regio-divergent carbosulfenylation of unactivated alkenes with electrophilic N-sulfenophthalimides has been developed. This protocol provides a straightforward and efficient access to various medium-sized rings, especially strained 7- and 8-membered carborings with a sulfur atom attached. The endo/exo selectivity in the reaction depends on the atom number of the chain between arene and alkene. Broad substrate scope, high yields, and gram-scale synthesis exemplified the utility and practicability of this protocol. In addition, this methodology can be extended to the carboselenylation of isolated alkenes.