240418-69-3

Basic information

• Product Name: cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside
• Synonyms: cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside
• CAS NO: 240418-69-3
• Molecular Weight: 328.43
• Mol File: 240418-69-3.mol

Chemical Properties

• CAS DataBase Reference: cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside(240418-69-3)
• EPA Substance Registry System: cyclohexyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-eno-1-thio-α-D-pyranoside(240418-69-3)

Safety Data

• Hazardous Substances Data: 240418-69-3(Hazardous Substances Data)

Upstream product

• 1569-69-3 Cyclohexanethiol 
• 2873-29-2 D-glucal triacetate 

Relevant articles and documents

Sm(OTf)3as a highly efficient catalyst for the synthesis of 2,3-unsaturated O- and S-pyranosides from glycals and the temperature-dependent formation of 4-O-acetyl-6-deoxy-2,3-unsaturated S-pyranosides and 4-O-acetyl-6-deoxy-3-alkylthio glycals

By using Sm(OTf)3as the catalyst, synthesis of 2,3-unsaturated-glycosides has been performed. A series of 2,3-unsaturated glycosides were obtained from 3,4,6-tri-O-acetyl-d-glucal or 3,4-di-O-acetyl-l-rhamnal under mild reaction conditions in g

Ruthenium Catalyzed Stereo/Chemo/Regioselective One-Pot Synthesis of C(2)-C(3) Unsaturated and α-d-Mannopyranosyl Sulfones

An efficient and divergent approach to C(2)-C(3) unsaturated glycosyl and α-d-mannopyranosyl sulfones has been developed via ruthenium-promoted direct glycosylation, oxidation, and dihydroxylation from glycal in one-pot. The presence of stoichiometric amounts of NaIO4 and in situ generation of RuO4 from a RuCl3-NaIO4 reagent system were crucial for chemoselective oxidation of sulfide in the presence of an olefin moiety. The dual-role of ruthenium in sequential glycosylation-oxidation-dihydroxylation is amenable to a wide range of thio acceptors to access α-d-mannopyranosyl sulfones in good yields with high regioselectivity.

RuCl3·3H2O as catalyst for Ferrier rearrangement: An efficient procedure for the preparation of pseudoglycosides

By using RuCl3·3H2O as catalyst, an improved method for the synthesis of 2,3-unsaturated-glycosides has been established. A series of 2, 3-unsaturated-glucosides were obtained from 2,4,6-tri-O-acetyl-d- glucal or 3,4-di-O-acetyl-6-deoxy-l-glucal in good yield and high anomeric selectivity.

CF3SO3H-SiO2 as catalyst for Ferrier rearrangement: An efficient procedure for the synthesis of pseudoglycosides

An efficient method for the conversion of 2,4,6-tri-O-acetyl-D-glucal to 2,3-unsaturated glycosides by using triflic acid on SiO2 as catalyst has been established. A series of 2,3-unsaturated glucosides were synthesized in good yield and high anomeric selectivity under transition metal-free conditions.