24199-58-4Relevant academic research and scientific papers
1-ADAMANTYLAZETIDIN-2-ONE DERIVATIVES AND DRUGS CONTAINING SAME
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Page/Page column 14, (2010/04/23)
It is to provide a novel compound useful for preventing and/or treating diseases that involves 11β-hydroxysteroid dehydrogenase 1, particularly diabetes, insulin resistance, diabetes complication, obesity, dyslipidemia, hypertension, fatty liver, or metab
Copper-nitrene complexes in catalytic C-H amination
Badiei, Yosra M.,Dinescu, Adriana,Dai, Xuliang,Palomino, Robert M.,Heinemann, Frank W.,Cundari, Thomas R.,Warren, Timothy H.
supporting information; experimental part, p. 9961 - 9964 (2009/05/07)
(Chemical Equation Presented) Hydrocarbons activate! Isolable β-diketiminato dicopper-nitrene complexes such as 1 derived from the reaction of [{(Cl2NN)Cu}2(μ-benzene)] and 1-adamantylazide are potent towards nitrene insertion into unactivated sp 3-hybridized C-H bonds. 1 allows stoichiometric and catalytic intermolecular C-H amination of hydrocarbons to give secondary amines (see scheme). Catalyst loadings as low as 0.05 mol% may be used.
SYNTHESIS AND TRANSFORMATIONS OF N-ADAMANTYL-SUBSTITUTED OXAZIRIDINES
Isaev, S. D.,Novoselov, E. F.,Yurchenko, A. G.
, p. 103 - 108 (2007/10/02)
N-Adamantyl-substituted oxaziridines were obtained by the oxidation of the Schiff bases synthesized from adamantyl-containing amines with peroxyacetic acid.The thermal rearrangement and fragmentation under the influence of Fe(II) ions, leading to nitrones
