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24211-55-0

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24211-55-0 Usage

General Description

(S)-3-Hydroxypiperidine is a crucial chemical compound used widely in organic synthesis and medicinal chemistry. Chemically, it is classified under the group of piperidines, which are heterocyclic organic compounds. Its unique structural and stereochemical attributes make it a critical building block in pharmaceutical research, particularly in the design and production of drugs. This particular isomer, marked by the (S)-3 prefix, indicates its specific molecular orientation, which can influence its chemical behavior, bioavailability, and efficacy in various applications. Handling of (S)-3-Hydroxypiperidine requires careful attention due to its potentially harmful effects and reactivity.

Check Digit Verification of cas no

The CAS Registry Mumber 24211-55-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,4,2,1 and 1 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 24211-55:
(7*2)+(6*4)+(5*2)+(4*1)+(3*1)+(2*5)+(1*5)=70
70 % 10 = 0
So 24211-55-0 is a valid CAS Registry Number.

24211-55-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (3S)-piperidin-3-ol

1.2 Other means of identification

Product number -
Other names (S)-piperidin-3-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:24211-55-0 SDS

24211-55-0Relevant articles and documents

Preparation method of (S)-3-hydroxypiperidine

-

Paragraph 0028, (2018/06/15)

The invention discloses a preparation method of (S)-3-hydroxypiperidine. The preparation method comprises the steps of (1) carrying out catalytic hydrogenation on 3-hydroxypyridine to prepare 3-hydroxypiperidine; (2) splitting the 3-hydroxypiperidine for preparing the (S)-3-hydroxypiperidine, wherein catalytic hydrogenation is carried out under the co-catalysis of a ruthenium/silicon dioxide catalyst and a cocatalyst; the weight ratio of the ruthenium/silicon dioxide catalyst to the cocatalyst is 1:1 to 3:1; the total weight of the ruthenium/silicon dioxide catalyst and the cocatalyst is 5 to10 percent of the weight of the 3-hydroxypiperidine; and the cocatalyst is aluminum oxide. According to the method provided by the invention, the ruthenium/silicon dioxide catalyst and the aluminum oxide are adopted as a compound catalyst for catalytic hydrogenation, and the compound catalyst is relatively cheap but has the same better catalysis effect, and pollutes environment less so as to be suitable for industrial production.

Concise Enantioselective Synthesis of Naturally Active (S)-3-Hydroxypiperidine

Dey, Soumen,Karabal, Pratibha U.,Sudalai, Arumugam

, p. 1559 - 1565 (2015/06/02)

A short and efficient enantioselective synthesis of natural product (S)-3-hydroxypiperidine has been achieved starting from commercially available raw materials employing two catalytic routes: (i) cocatalyzed hydrolytic kinetic resolution (HKR) of racemic methyl-3-(oxiran-2-yl)propanoate; (ii) proline-catalyzed α-aminooxylation followed by Horner-Wardsworth-Emmons olefination in high enantiomeric purity (97% ee) and high overall yield (38%). (Chemical Equation Presented).

Asymmetric syntheses of pyrrolidine and piperidine derivatives Via regio-and stereo-selective ring-opening reactions of chiral aziridine

Higashiyama, Kimio,Matsumura, Masataka,Kurita, Emiko,Yamauchi, Takayasu

, p. 371 - 380 (2013/08/15)

Asymmetric synthesis of cyclic β-amino alcohols (pyrrolidine and piperidine derivatives) has been achieved using a chiral aziridine as the starting material. The key step of this synthetic methodology is regio- and stereo-controlled ring-opening of the chiral aziridine with acetic acid or acetyl chloride.

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