24237-71-6Relevant academic research and scientific papers
A three-component reaction of arynes, sodium sulfinates, and aldehydes toward 2-sulfonyl benzyl alcohol derivatives
Chen, Qian,Gao, Yang,Hu, Yifan,Huang, Yuanting,Li, Xianwei,Zhao, Xi
, p. 7066 - 7073 (2021/08/25)
A novel three-component reaction of arynes, sodium sulfinates, and aldehydes under mild reaction conditions is described. This transformation provides a direct synthetic approach to 2-sulfonyl benzyl alcohol derivatives, which could be rapidly converted to diverse arylsulfur compounds via the transformation of the corresponding hydroxyl groups. Various aryne precursors, sodium arenesulfinates, and aromatic aldehydes can be effectively converted to the desired products in 40-84% yields (29 examples).
Reactions of Sulfoxides Bearing ortho-Sulfur Functional Groups and Thianthrene Monoxide with Grignard Reagents
Furukawa, Naomichi,Ogawa, Satoshi,Matsumura, Kazunori,Shibutani, Tadao,Fujihara, Hisashi
, p. 979 - 982 (2007/10/02)
Diaryl sulfoxides bearing ortho-sulfur substituents react readily with Grignard reagents on the sulfur atom to produce the corresponding phenyl Grignard reagents bearing ortho-sulfur functional group.Furthermore, thianthrene monooxide was found to react with alkyl Grignard reagents affording o,o'-bis-Grignard reagent of diphenyl sulfide which was converted easily to Martin's sulfurane.
