24337-33-5Relevant academic research and scientific papers
ALPHA CARBOCATION STABILIZATION BY SILICON, GERMANIUM AND TIN
Soderquist, John A.,Hassner, Alfred
, p. 1899 - 1902 (1988)
The hydrolyses of a number of α-metalloidal vinyl ethers were found to undergo a ratel-imiting protonation to produce α- silil, germyl or stannyl carbocations.Comparative rate data leads to the ordering: C>Sn>Ge>Si>H, for the stabilization of such intermediates.
