ALPHA CARBOCATION STABILIZATION BY SILICON, GERMANIUM AND TIN

DOI: 10.1016/S0040-4039(00)82072-9

Source and publish data:

Tetrahedron Letters p. 1899 - 1902 (1988)

Update date:2022-08-05

Topics:

Authors:

Soderquist, John A.

Hassner, Alfred

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Article abstract of DOI:10.1016/S0040-4039(00)82072-9

The hydrolyses of a number of α-metalloidal vinyl ethers were found to undergo a ratel-imiting protonation to produce α- silil, germyl or stannyl carbocations.Comparative rate data leads to the ordering: C>Sn>Ge>Si>H, for the stabilization of such intermediates.

Full text of DOI:10.1016/S0040-4039(00)82072-9

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