Tetrahedron Letters p. 1899 - 1902 (1988)
Update date:2022-08-05
Topics:
Soderquist, John A.
Hassner, Alfred
The hydrolyses of a number of α-metalloidal vinyl ethers were found to undergo a ratel-imiting protonation to produce α- silil, germyl or stannyl carbocations.Comparative rate data leads to the ordering: C>Sn>Ge>Si>H, for the stabilization of such intermediates.
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