243672-16-4Relevant academic research and scientific papers
Highly anti-selective SN2′ substitutions of chiral cyclic 2-lodo-allylic alcohol derivatives with mixed zinc-copper reagents
Calaza, M. Isabel,Hupe, Eike,Knochel, Paul
, p. 1059 - 1061 (2007/10/03)
(Figure presented) Functionalized allylic electrophilic reagents such as chiral 2-iodo-1-cyclohexenyl and -cyclopentenyl phosphates undergo highly stereoselective anti-SN2′-allylic substitution reactions with a wide range of organozinc reagents
Asymmetric hydroboration with new chiral monoalkylboranes bearing a non- stereogenic, chirotopic center
Graf, Claus-Dieter,Knochel, Paul
, p. 8801 - 8814 (2007/10/03)
Enantiomerically pure 2,5-diorganocyclopentanecarboxylic acids bearing a non-stereogenic, chirotopic center were prepared via stereoselective copper catalyzed carbon-carbon bond forming reactions. These compounds serve as intermediates in the synthesis of
