243990-73-0

Basic information

• Product Name: 2,2-dimethyl-propionic acid 1-(2,5-dichloro-phenyl)-2,2-bis-methylsulfanyl-vinyl ester
• Synonyms: 2,2-dimethyl-propionic acid 1-(2,5-dichloro-phenyl)-2,2-bis-methylsulfanyl-vinyl ester
• CAS NO: 243990-73-0
• Molecular Weight: 365.345
• Mol File: 243990-73-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-dimethyl-propionic acid 1-(2,5-dichloro-phenyl)-2,2-bis-methylsulfanyl-vinyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dimethyl-propionic acid 1-(2,5-dichloro-phenyl)-2,2-bis-methylsulfanyl-vinyl ester(243990-73-0)
• EPA Substance Registry System: 2,2-dimethyl-propionic acid 1-(2,5-dichloro-phenyl)-2,2-bis-methylsulfanyl-vinyl ester(243990-73-0)

Safety Data

• Hazardous Substances Data: 243990-73-0(Hazardous Substances Data)

Upstream product

• 3282-30-2 pivaloyl chloride 
• 171897-89-5 1-(2,5-Dichlorophenyl)-2,2-bis(methylsulfanyl)ethanone 

Downstream Products

• 16474-43-4 pivalic acid tert-butyl ester 
• 2094-69-1 benzyl pivalate 
• 5434-57-1 n-Hexyl pivalate 
• 183280-13-9 para-fluorophenyl pivalate 
• 26209-45-0 N-benzyl-2,2-dimethylpropanamide 

Relevant articles and documents

1-(2,5-dichlorophenyl)-2,2-bis(methylsulfanyl)vinyl esters as highly efficient chemoselective acylating reagents

1-(2,5-Dichlorophenyl)-2,2-bis(methylsulfanyl)vinyl esters 4f-k were prepared in yields usually greater than 90%, by reacting acyl chlorides with 1-(2,5-dichlorophenyl)-2,2-bis(methylsulfanyl)ethanone enolate. These esters were demonstrated to be excellent chemoselective reagents for the acylation of amines, alcohols, thiols, pyrrole and indole. From all the acylation reactions the dimethyl α-oxo dithioacetal 2d, recyclable for the preparation of esters 4f-k, could be recovered in 90-100% yield.