24470-76-6

Basic information

• Product Name: bis(2-methylpropyl)mercury
• Synonyms: Bis(isobutyl)mercury
• CAS NO: 24470-76-6
• Molecular Formula: C₈H₁₈Hg
• Molecular Weight: 314.8185
• Mol File: 24470-76-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(2-methylpropyl)mercury(CAS DataBase Reference)
• NIST Chemistry Reference: bis(2-methylpropyl)mercury(24470-76-6)
• EPA Substance Registry System: bis(2-methylpropyl)mercury(24470-76-6)

Safety Data

• Hazardous Substances Data: 24470-76-6(Hazardous Substances Data)

Upstream product

• 78-77-3 Isobutyl bromide 
• 513-38-2 Isobutyl iodide 
• 100-99-2 triisobutylaluminum 
• 5674-02-2 2-methylpropylmagnesium chloride 
• 105115-72-8 C₆H₅SCH₂HgCl 
• 27151-74-2 isobutylmercury chloride 
• 930-81-4 1-norbornyllithium 

Downstream Products

• 100-99-2 triisobutylaluminum 
• 101-81-5 Diphenylmethane 
• 5267-35-6 N-(diphenylmethyl)acetamide 
• 51507-36-9 (3-methylbut-2-ene-1,1-diyl)dibenzene 
• 115-11-7 isobutene 
• 22233-92-7 2-methyl-1-propyl phenyl selenide 
• 519-73-3 triphenylmethane 
• 28859-82-7 isobutylmercury(II) bromide 
• 76-84-6 triphenylmethyl alcohol 
• 78504-78-6 isobutyl triphenylmethyl peroxide 
• 596-30-5 ditrityl peroxide 

Relevant articles and documents

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UEBER EINE trans-EINFLUSS-REIHE DER ORGANYLANIONEN AUS 13C-NMR-SPEKTROSKOPISCHEN UNTERSUCHUNGEN VON ORGANYLQUECKSILBERISOBUTYLVERBINDUNGEN

The 1J(199Hg-13C) coupling constants of isobutylmercury compounds RHgCH2CHMe2 (R=organo group) have been measured and compared to the coupling constants of diisobutylmercury and diorganomercury compounds HgR2.Between the coupling constants 1J(Hg-Ci-Bu) and 1J(Hg-CR), which have been normalized to the coupling constants of the symmetric compounds concerned, a linear relation has been found.This relation, which can be deduced from the Fermi contact term on the basis of the simple hybrid orbital model, shows that the coupling constant 1J(Hg-Ci-Bu) reflects the s-character of the mercury hybrid orbital concerned and accordingly the NMR trans-influence of the organo group R.The NMR trans-influence decreases in the sequence t-Bu > i-Pr ca. cyclo-C6H11 > Et ca. n-Pr ca. n-Bu ca. i-Bu > CH2Ph ca.CH2CH=CH2 ca.Me > CH2SiMe3 > Ph ca.CH=CH2 > CH2SPh > CCl3 > C6Cl5 > CCPh ca.CCH.