245111-14-2Relevant academic research and scientific papers
Highly phosphonated poly(N-phenylacrylamide) for proton exchange membranes
Fukuzaki, Namiko,Nakabayashi, Kazuhiro,Nakazawa, Satoshi,Murata, Shigeaki,Higashihara, Tomoya,Ueda, Mitsuru
experimental part, p. 93 - 100 (2011/10/08)
A novel highly phosphonated poly(N-phenylacrylamide) (PDPAA) with an ion-exchange capacity (IEC) of 6.72 mequiv/g was synthesized by the radical polymerization of N-[2,4-bis(diethoxyphosphinoyl)phenyl]acrylamide (DEPAA), followed by the hydrolysis with tr
Direct synthesis of amino-substituted aromatic phosphonates via palladium-catalyzed coupling of aromatic mono-and dibromides with diethyl phosphite
Bessmertnykh, Alla,Douaihy, Christiane Morkos,Guilard, Roger
supporting information; experimental part, p. 738 - 739 (2011/04/21)
An efficient Pd-catalyzed carbon-phosphorus bond-forming route is described for the direct synthesis of diethyl arylphosphonates bearing amino and alkylamino groups on the aromatic ring. Copyright
Direct phosphonylation of mono- and dihalogenoanilines
Defacqz, Nathalie,De Bueger, Bruno,Touillaux, Roland,Cordi, Alex,Marchand-Brynaert, Jacqueline
, p. 1368 - 1372 (2007/10/03)
The Pd(0)-catalyzed coupling reaction of diethyl phosphite to bromoaniline precursors or derivatives could not be realized at the ortho- position. On the other hand, the photoactivated substitution with diethyl phosphite anion was readily applied to unprotected mono- and dihalogenoanilines; the ortho-substitution was more rapid than the para, but side-products resulting from dehalogenation reactions were also formed. New fluorophosphonoanilines 8 and diphosphonoanilines 9 have been prepared.
