245349-46-6

Basic information

• Product Name: 4-(3-ACRYLOYLOXY-N-PROP-1-YLOXY)BENZOIC ACID
• Synonyms: 4-(3-ACRYLOYLOXY-N-PROP-1-YLOXY)BENZOIC ACID;4-(3-(acryloyloxy)propoxy)benzoic acid;4-(3-(acryloyloxy)propyloxy)benzoic acid;4-(3-prop-2-enoyloxypropoxy)benzoic acid
• CAS NO: 245349-46-6
• Molecular Formula: C₁₃H₁₄O₅
• Molecular Weight: 250.2473
• Product Categories: API intermediates
• Mol File: 245349-46-6.mol

Chemical Properties

• Boiling Point: 428.1 °C at 760 mmHg
• Flash Point: 162.9 °C
• Appearance: /
• Density: 1.208 g/cm³
• PKA: 4.44±0.10(Predicted)
• CAS DataBase Reference: 4-(3-ACRYLOYLOXY-N-PROP-1-YLOXY)BENZOIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(3-ACRYLOYLOXY-N-PROP-1-YLOXY)BENZOIC ACID(245349-46-6)
• EPA Substance Registry System: 4-(3-ACRYLOYLOXY-N-PROP-1-YLOXY)BENZOIC ACID(245349-46-6)

Safety Data

• Hazardous Substances Data: 245349-46-6(Hazardous Substances Data)

Usage

Preparation

The preparation of 4-(3-acryloyloxy-n-prop-1-yloxy)benzoic acid is as follows:8.1g Allyl 4- (3- (acryloyloxy) propoxy) benzoic acid,4.1 g of N-methylaniline,Add 0.28 g of palladium acetate and 0.66 g of triphenylphosphine to 50 mL of acetonitrile, andStir at room temperature overnight. The reaction solution is diluted with ethyl acetate,The extract was washed with 5% hydrochloric acid and saturated brine, dried over anhydrous sodium sulfate, the solid was filtered off, and the solvent was evaporated. The residue is purified by column chromatography (silica gel, developing solvent: dichloromethane) to yield 4.2 g of 4- (3- (Acryloyloxy) propoxy) benzoic acid(Yield: 80.0%, purity (HPLC): 93.0%) was obtained.

Upstream product

• 18982-18-8 allyl 4-hydroxybenzoate 
• 46350-87-2 4-(3-hydroxypropyloxy)benzoic acid 
• 292638-85-8 acrylic acid methyl ester 
• 99-76-3 methyl 4-hydroxylbenzoate 
• 99-96-7 4-hydroxy-benzoic acid 
• 46731-01-5 ethyl 4-(3-hydroxypropyloxy)benzoate 
• 814-68-6 acryloyl chloride 
• 120-47-8 Ethyl 4-hydroxybenzoate 
• 79-10-7 acrylic acid 

Downstream Products

• 1245062-25-2 3-(perfluorooctyl)propyl 4-(3-acryloyloxypropyloxy)benzoate 
• 174063-87-7 2-methylbenzene-1,4-diyl bis{4-[3-(acryloyloxy)propoxy]benzoate} 

Relevant articles and documents

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