246159-75-1

Upstream product

• 246159-73-9 2-(3-O-tert-butyldimethylsilyl-2,6-dideoxy-β-D-arabino-hexofuranosyl)-1-hydroxy-5,8-dimethoxynaphthalene 
• 246159-58-0 2-(2,6-dideoxy-β-D-arabino-hexofuranosyl)-1-hydroxy-5,8-dimethoxynaphthalene 
• 161258-49-7 2-(3',4'-di-O-acetyl-2',6'-dideoxy-β-D-arabino-hexopyranosyl)-5,8-dimethoxynaphthalen-1-ol 
• 98-88-4 benzoyl chloride 

Downstream Products

• 246159-76-2 1-benzoyloxy-2-[4-O-benzoyl-3-O-(4-O-acetyl-2,3,6-trideoxy-α-L-threo-hex-2-enopyranosyl)-2,6-dideoxy-β-D-arabino-hexofuranosyl]-5,8-dimethoxynaphthalene 

Relevant academic research and scientific papers

Naphthalene disaccharide fragments as building blocks for angucycline synthesis

Methods for the construction of naphthalene oligodeoxy disaccharide fragments, common structural elements of the angucycline antibiotics, are investigated. The triphenylphosphonium bromide-or scandium triflate-catalyzed addition of rhodinal to 4-OH silyl-protected olivoses affords the required 3-O-α-oligodeoxy disaccharides selectively and in high yields.