Naphthalene disaccharide fragments as building blocks for angucycline synthesis

Article abstract of DOI:10.1080/07328309908544037

Methods for the construction of naphthalene oligodeoxy disaccharide fragments, common structural elements of the angucycline antibiotics, are investigated. The triphenylphosphonium bromide-or scandium triflate-catalyzed addition of rhodinal to 4-OH silyl-protected olivoses affords the required 3-O-α-oligodeoxy disaccharides selectively and in high yields.

Full text of DOI:10.1080/07328309908544037

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Journal of Carbohydrate Chemistry
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Naphthalene Disaccharide
Fragments as Building Blocks for
Angucycline Synthesis
Karsten Krohn & Christiane Bäuerlein
a Fachbereich Chemie und Chemietechnik, Universität-GH
Paderborn , Warburger Str. 100, D-33098 Paderborn, Germany
E-mail:
b Fachbereich Chemie und Chemietechnik, Universität-GH
Paderborn , Warburger Str. 100, D-33098 Paderborn, Germany
E-mail:
Published online: 27 Feb 2008.
To cite this article: Karsten Krohn & Christiane Bäuerlein (1999) Naphthalene Disaccharide
Fragments as Building Blocks for Angucycline Synthesis, Journal of Carbohydrate Chemistry,
18:7, 807-831, DOI: 10.1080/07328309908544037
To link to this article: http://dx.doi.org/10.1080/07328309908544037
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