247244-37-7Relevant academic research and scientific papers
α-Functionalised ketones as promoters of alkene epoxidation by oxone
Armstrong, Alan,Hayter, Barry R.
, p. 11119 - 11126 (1999)
Acceleration of Oxone epoxidation of alkenes by several α- functionalised ketones, including α-amido ketones, is investigated. In general, competing decomposition by Baeyer-Villiger reaction prevents use of the ketones as efficient epoxidation promoters.
Diastereoselective [4+3] cycloadditions of enantiopure nitrogen-stabilized oxyallyl cations
MaGee, David I.,Godineau, Edouard,Thornton, Paul D.,Walters, Michael A.,Sponholtz, Deborah J.
, p. 3667 - 3680 (2007/10/03)
Diastereoselective trapping of chiral enantiopure oxyallyl cations by common dienes is reported. Excellent diastereoselectivities were obtained and depending on which auxiliary was used cycloadditions proceeded through a chelated or non-chelated pathway.
