247256-58-2

Upstream product

• 5674-02-2 2-methylpropylmagnesium chloride 
• 247256-57-1 (3R,1'S,2'S)-5-tert-Butyldiphenylsiloxy-3-methyl-3-(1'-phenyl-2'-trifluoroacetamido-1'-propoxy)-1-pentanal 
• 214959-70-3 (3S,1'S,2'S)-1-tert-Butyldiphenylsiloxy-3-methyl-3-(1'-phenyl-2'-trifluoroacetamido-1'-propoxy)hex-5-en 
• 183378-05-4 trimethylsilyl ether of (1S,2S)-N-trifluoroacetamidonorpseudoephedrine 
• 97250-25-4 tert-Butyldiphenylsilyl β-hydroxybutanone 

Downstream Products

• 247256-60-6 (3R,5RS)-1-tert-Butyldiphenylsiloxy-3,7-dimethyl-3,5-octanediol p-methoxybenzylidenacetal 
• 247256-63-9 (4S,6RS)-4,8-Dimethyl-1-furan-3'-ylnonane-1-on-4,6-diol p-methoxybenzylideneacetal 
• 247256-62-8 (3R,5RS)-3,7-Dimethyl-1-iodo-3,5-octanediol p-methoxybenzylidenacetal 
• 247256-61-7 (3R,5RS)-3,7-Dimethyl-1,3,5-octanetriol-3,5-p-methoxybenzylidenacetal 
• 55626-95-4 athanagrandione 
• 247256-59-3 (3R,5RS)-1-tert-Butyldiphenylsiloxy-3,7-dimethyl-3,5-octanediol 

Relevant academic research and scientific papers

First total synthesis and determination of the absolute configuration of the stress factor (+)-hydroxymyoporone

The first total synthesis of the stress factor (+)-hydroxymyoporone (4) is presented. The key step is an asymmetric allylation of the methyl ketone 10 which proceeds with excellent selectivity and yield. In addition, it was proven that the assignment of t