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SYNTHESE ET CYCLISATION OXYDANTE DE TRIENE-2,3,5 OLS-1 EN HYDROXYALKYL-5 CYCLOPENTENE-2 ONES-1
Douthreau, Alain,Sartoretti, Jacques,Gore, Jacques
, p. 3059 - 3066 (1983)
Five 2,3,5 trien-1 ols, have been prepared by three different ways.Their reaction with t-butyl peroxide in the presence of catalytic amounts of vanadyl acetylacetonate yields mainly the cyclopentenones 2.This sequence provides a new route to methylenomycine B 3.
