SYNTHESE ET CYCLISATION OXYDANTE DE TRIENE-2,3,5 OLS-1 EN HYDROXYALKYL-5 CYCLOPENTENE-2 ONES-1

DOI: 10.1016/S0040-4020(01)91546-7

Source and publish data:

Tetrahedron p. 3059 - 3066 (1983)

Update date:2022-08-16

Topics:

Authors:

Douthreau, Alain

Sartoretti, Jacques

Gore, Jacques

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Article abstract of DOI:10.1016/S0040-4020(01)91546-7

Five 2,3,5 trien-1 ols, have been prepared by three different ways.Their reaction with t-butyl peroxide in the presence of catalytic amounts of vanadyl acetylacetonate yields mainly the cyclopentenones 2.This sequence provides a new route to methylenomycine B 3.

Full text of DOI:10.1016/S0040-4020(01)91546-7

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