24838-27-5Relevant academic research and scientific papers
Photolysis of 2-Amino-2'-azidobiphenyls: Formal Formation of Internally Trapped Didehydroazepines
Murata, Shigeru,Tsuji, Hiroshi,Tomioka, Hideo
, p. 895 - 897 (1994)
Photolysis of 2-amino-2'-azidobiphenyls in diethylamine gave 4,10-dihydroazepinoindoles (7), the structure of which corresponded to the didehydroazepines formally trapped with an internal amino group.However, the yields of 7 were considered low, which was due to the significant intramolecular interaction of the photolytically generated nitrene with an amino group, to afford benzocinnoline as a final product.
