24897-32-3

Basic information

• Product Name: C₁₀H₁₄O
• CAS NO: 24897-32-3
• Molecular Weight: 150.221
• Mol File: 24897-32-3.mol

Chemical Properties

• CAS DataBase Reference: C₁₀H₁₄O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₀H₁₄O(24897-32-3)
• EPA Substance Registry System: C₁₀H₁₄O(24897-32-3)

Safety Data

• Hazardous Substances Data: 24897-32-3(Hazardous Substances Data)

Upstream product

• 1192-88-7 1-cyclohexene-1-carboxaldehyde 
• 16466-97-0 1-propynylmagnesium bromide 

Downstream Products

• 1392141-34-2 1-cyclohexenyl-2-butyn-1-yl pivalate 
• 1450915-80-6 1-(1-(vinyloxy)but-2-yn-1-yl)cyclohex-1-ene 

Relevant articles and documents

Rh-Catalyzed [5+1] and [4+1] cycloaddition reactions of 1,4-enyne esters with co: A shortcut to functionalized resorcinols and cyclopentenones

We have developed novel Rh-catalyzed [n+1]-type cycloadditions of 1,4-enyne esters, which involve an acyloxy migration as a key step. The efficient preparation of functionalized resorcinols, including biaryl derivatives, from readily available 1,4-enyne esters and CO was achieved by Rh-catalyzed [5+1] cycloaddition accompanied by 1,2-acyloxy migration. When enyne esters had an internal alkyne moiety, the reaction proceeded by a [4+1]-type cycloaddition involving 1,3-acyloxy migration, leading to cyclopentenones.