250138-84-2

Upstream product

• 203715-36-0 (5R,6R)-5,6-dihydroxydeca-1,9-diene 
• 100-39-0 benzyl bromide 
• 39139-91-8 trans-1,5,9-decatriene 
• 250138-82-0 (2R,2R',5R, 5R')-5,5'-bis(hydroxymethyl)octahydro-2,2'-bifuran 

Downstream Products

• 261617-87-2 (2R,5R,6R,9R,10R)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol 
• 250138-85-3 1-((2R,5R,2'R,5'R)-5'-Benzyloxymethyl-octahydro-[2,2']bifuranyl-5-yl)-pent-4-en-1-one 
• 337954-15-1 (1R,5S,2'R,5'R,2''R,5''R)-1-[5'-(5''-Benzyloxymethyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-1,5-di(tert-butyldimethylsilyloxy)undecane 
• 337954-05-9 (5S,2'R,5'R,2''R,5''R)-1-[5'-(5''-Benzyloxymethyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-5-(tert-butyldimethylsilyloxy)undecan-1-one 
• 337954-06-0 (1R,5S,2'R,5'R,2''R,5''R)-1-[5'-(5''-Benzyloxymethyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-5-(tert-butyldimethylsilyloxy)undecan-1-ol 
• 292820-19-0 (1R,2'R,5'R,2''R,5''R,1'''R,5'''S)-1-[5'-(5''-(1''',5'''-Di(tert-butyldimethylsilyloxy)undecan-1'''-yl)tetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]-13-(2'''',3'''',4'''',5''''-tetramethoxy-6''''-methylphenyl)tridecan-1-ol 
• 292820-14-5 Hydroquinone-squamocin D dimethyl ether 

Relevant academic research and scientific papers

Quinone - Annonaceous acetogenins: Synthesis and complex I inhibition studies of a new class of natural product hybrids

The natural product hybrids quinone-mucocin and quinone- squamocin D were synthesized. In these hybrids, the butenolide unit of the annonaceous acetogenins mucocin and squamocin D is exchanged for the quinone moiety of the natural complex I substrate ubiq

A facile route to bulladecin-type acetogenins - Total synthesis of asimilobin and correction of the configuration of its tetrahydrofuran segment

The most efficient method for the synthesis of the trans/threo/trans- bis(tetrahydrofuran) (THF) ring unit was established, and the first total synthesis of (-)-asimilobin and its diastereomer was then accomplished in twelve and fourteen steps, respectively, from trans-1,5,9-decatriene, by a convergent route with a Wittig reaction as the key step. By virtue of these synthetic results, the absolute configuration of the bis(THF) unit in naturally occurring asimilobin should be corrected.

Stereocontrolled construction of the trans tetrahydrofuran units in Annonaceous acetogenins

An efficient synthetic method for the construction of trans- tetrahydrofuran (THF) unit from trans-1,5,9-decatriene was successfully developed by means of Sharpless AD reactions and oxidative cyclizations catalyzed by Co(modp)2 under an oxygen