261617-87-2

Basic information

• Product Name: (2R,5R,6R,9R,10R)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol
• Synonyms: (2R,5R,6R,9R,10R)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol
• CAS NO: 261617-87-2
• Molecular Weight: 488.751
• Mol File: 261617-87-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,5R,6R,9R,10R)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,5R,6R,9R,10R)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol(261617-87-2)
• EPA Substance Registry System: (2R,5R,6R,9R,10R)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol(261617-87-2)

Safety Data

• Hazardous Substances Data: 261617-87-2(Hazardous Substances Data)

Upstream product

• 110220-87-6 n-tetradecylmagnesium chloride 
• 250138-84-2 (all-R)-5'-(5''-Benzyloxymethyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-carbaldehyde 
• 250138-83-1 (all-R)-[5'-(5''-Benzyloxymethyltetrahydrofuran-2''-yl)tetrahydrofuran-2'-yl]methanol 
• 250138-82-0 (2R,2R',5R, 5R')-5,5'-bis(hydroxymethyl)octahydro-2,2'-bifuran 
• 203715-36-0 (5R,6R)-5,6-dihydroxydeca-1,9-diene 
• 100-39-0 benzyl bromide 
• 39139-91-8 trans-1,5,9-decatriene 
• 261617-85-0 (2R,5R,6R,9R)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanone 

Relevant articles and documents

A facile route to bulladecin-type acetogenins - Total synthesis of asimilobin and correction of the configuration of its tetrahydrofuran segment

The most efficient method for the synthesis of the trans/threo/trans- bis(tetrahydrofuran) (THF) ring unit was established, and the first total synthesis of (-)-asimilobin and its diastereomer was then accomplished in twelve and fourteen steps, respectively, from trans-1,5,9-decatriene, by a convergent route with a Wittig reaction as the key step. By virtue of these synthetic results, the absolute configuration of the bis(THF) unit in naturally occurring asimilobin should be corrected.