250226-89-2

Upstream product

• 81972-20-5 2-(2',3',4',6'-tetra-O-benzyl-β-D-glucopyranosyl)ethanol 
• 96689-97-3 (2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-ethanal 
• 441352-30-3 2,2-Dimethyl-propionic acid 2-((2R,4aR,6S,7R,8R,8aS)-7,8-dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl)-ethyl ester 
• 250226-85-8 2,2-Dimethyl-propionic acid 2-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl ester 
• 250226-87-0 2-[(2S,3S,4R,5R,6R)-3,4-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-ethanol 
• 250226-86-9 2,2-Dimethyl-propionic acid 2-((2S,3S,4S,5R,6R)-3,4-bis-benzyloxy-5-hydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yl)-ethyl ester 
• 82614-10-6 ethyl 2-((2S,3S,4R,5R,6R)-3,4,5-tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-yl)acetate 
• 250226-88-1 [(2R,3R,4R,5S,6S)-4,5-Bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-yl]-methanol 

Downstream Products

• 250226-65-4 [(3S,4R,5S,6S)-4,5-Bis-benzyloxy-6-(2-methoxymethoxy-ethyl)-2-methylene-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 
• 441352-41-6 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-4,8-bis-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-3-ol 
• 351186-86-2 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-3-allyloxy-4,8-bis-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 351186-85-1 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-3,4,8-tris-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 351186-84-0 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-3,4,8-tris-benzyloxy-9-benzyloxymethyl-5a-methoxy-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 351186-83-9 2-((2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4,8-Tris-benzyloxy-9-benzyloxymethyl-5a-methoxy-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl)-ethanol 
• 250226-67-6 [(2R,3R,4R,5S,6S)-4,5-Bis-benzyloxy-2-((5S,6R)-5-benzyloxy-6-benzyloxymethyl-5,6-dihydro-4H-pyran-2-ylmethyl)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 
• 250226-81-4 [(2R,3R,4R,5S,6S)-4,5-Bis-benzyloxy-2-((6S,7R)-6-benzyloxy-7-benzyloxymethyl-4,5,6,7-tetrahydro-oxepin-2-ylmethyl)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 
• 250226-68-7 (2S,3R,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-oxepan-3-ol 
• 441352-22-3 (2S,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-oxepan-3-one 
• 441352-51-8 2-((2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4,8-Tris-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl)-ethanol 
• 441352-37-0 2,2-Dimethyl-propionic acid 2-((2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4,8-tris-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl)-ethyl ester 
• 441352-24-5 (2S,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-dihydro-pyran-3-one 
• 441352-36-9 (2S,3R,5S,6R)-5-Benzyloxy-6-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-tetrahydro-pyran-3-ol 

Relevant academic research and scientific papers

A general strategy for the convergent synthesis of fused polycyclic ethers via B-alkyl Suzuki coupling: Synthesis of the ABCD ring fragment of ciguatoxins

A new method for convergent coupling of fused polycyclic ethers has been developed, which relies on B-alkyl Suzuki crosscoupling of lactone-derived enol triflates or phosphates. The strategy was successfully applied to a convergent synthesis of the ABCD r

A general method for convergent synthesis of polycyclic ethers based on Suzuki cross-coupling: Concise synthesis of the ABCD ring system of ciguatoxin

(matrix presented) A general method for convergent assembly of polyether structure has been developed based on palladium(0)-mediated Suzuki cross-coupling reaction of alkylboranes with cyclic ketene acetal phosphates. The present method allowed for coupli