441352-22-3

Basic information

• Product Name: (2S,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-oxepan-3-one
• Synonyms: (2S,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-oxepan-3-one
• CAS NO: 441352-22-3
• Molecular Weight: 869.18
• Mol File: 441352-22-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-oxepan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-oxepan-3-one(441352-22-3)
• EPA Substance Registry System: (2S,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-oxepan-3-one(441352-22-3)

Safety Data

• Hazardous Substances Data: 441352-22-3(Hazardous Substances Data)

Upstream product

• 22900-10-3 2-deoxy-D-ribose 
• 441352-38-1 Triisopropyl-[4-((2R,4S,5R)-5-methoxymethoxy-2-phenyl-[1,3]dioxan-4-yl)-butoxy]-silane 
• 441352-39-2 (5S,6R)-5,7-Bis-benzyloxy-6-methoxymethoxy-heptan-1-ol 
• 910658-46-7 (E)-(5S,6R)-5,6,7-Trihydroxy-hept-2-enoic acid methyl ester 
• 78606-80-1 5(S), 6(R), 7-trihydroxyheptanoic acid methyl ester 
• 116237-17-3 4-((2R,4S,5R)-5-Hydroxy-2-phenyl-[1,3]dioxan-4-yl)-butyric acid methyl ester 
• 100-39-0 benzyl bromide 
• 250226-81-4 [(2R,3R,4R,5S,6S)-4,5-Bis-benzyloxy-2-((6S,7R)-6-benzyloxy-7-benzyloxymethyl-4,5,6,7-tetrahydro-oxepin-2-ylmethyl)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 
• 250226-85-8 2,2-Dimethyl-propionic acid 2-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-ethyl ester 
• 250226-87-0 2-[(2S,3S,4R,5R,6R)-3,4-Bis-benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-dimethyl-silanyloxymethyl)-tetrahydro-pyran-2-yl]-ethanol 
• 250226-89-2 [(2S,3S,4R,5S,6S)-4,5-Bis-benzyloxy-2-iodomethyl-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 
• 250226-88-1 [(2R,3R,4R,5S,6S)-4,5-Bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-yl]-methanol 
• 351186-81-7 Phosphoric acid (6S,7R)-6-benzyloxy-7-benzyloxymethyl-4,5,6,7-tetrahydro-oxepin-2-yl ester diphenyl ester 
• 250226-65-4 [(3S,4R,5S,6S)-4,5-Bis-benzyloxy-6-(2-methoxymethoxy-ethyl)-2-methylene-tetrahydro-pyran-3-yloxy]-tert-butyl-dimethyl-silane 

Downstream Products

• 441352-41-6 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-4,8-bis-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-3-ol 
• 351186-86-2 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-3-allyloxy-4,8-bis-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 351186-85-1 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-3,4,8-tris-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 351186-84-0 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-3,4,8-tris-benzyloxy-9-benzyloxymethyl-5a-methoxy-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 441352-42-7 (2S,6S,7R)-6-Benzyloxy-7-benzyloxymethyl-2-[(2R,3R,4R,5S,6S)-4,5-bis-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(2-methoxymethoxy-ethyl)-tetrahydro-pyran-2-ylmethyl]-6,7-dihydro-oxepin-3-one 
• 441352-37-0 2,2-Dimethyl-propionic acid 2-((2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4,8-tris-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl)-ethyl ester 
• 441352-51-8 2-((2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4,8-Tris-benzyloxy-9-benzyloxymethyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl)-ethanol 
• 441352-49-4 (2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-2-Allyl-3,4,8-tris-benzyloxy-9-benzyloxymethyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalene 
• 441352-45-0 2-((2S,3S,4R,4aR,5aR,8S,9R,10aS,11aR)-3,4,8-Tris-benzyloxy-9-benzyloxymethyl-2,3,4,4a,5a,8,9,10a,11,11a-decahydro-1,5,10-trioxa-cyclohepta[b]naphthalen-2-yl)-ethanol 
• 441352-20-1 [(2R,4aR,5aS,6aR,8S,9S,10R,10aR,11aR,13aS)-8-Allyl-9-allyloxy-2-(4-methoxy-phenyl)-4a,5a,6,6a,8,9,10,10a,11a,13a-decahydro-4H-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-10-yloxy]-triisopropyl-silane 
• 441352-50-7 (2R,4aR,5aS,6aR,8S,9R,10R,10aS,11aR,13aS)-8-Allyl-2-(4-methoxy-phenyl)-4a,5a,6,6a,8,9,10,10a,11a,13a-decahydro-4H-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalene-9,10-diol 

Relevant articles and documents

A general strategy for the convergent synthesis of fused polycyclic ethers via B-alkyl Suzuki coupling: Synthesis of the ABCD ring fragment of ciguatoxins

A new method for convergent coupling of fused polycyclic ethers has been developed, which relies on B-alkyl Suzuki crosscoupling of lactone-derived enol triflates or phosphates. The strategy was successfully applied to a convergent synthesis of the ABCD r