250226-97-2

Upstream product

• 116237-16-2 4-((2R,4S,5R)-5-Hydroxy-2-phenyl-[1,3]dioxan-4-yl)-butyric acid 
• 22900-10-3 2-deoxy-D-ribose 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 910658-46-7 (E)-(5S,6R)-5,6,7-Trihydroxy-hept-2-enoic acid methyl ester 
• 1206828-93-4 C₁₄H₂₀O₄ 
• 78606-80-1 5(S), 6(R), 7-trihydroxyheptanoic acid methyl ester 
• 116237-17-3 4-((2R,4S,5R)-5-Hydroxy-2-phenyl-[1,3]dioxan-4-yl)-butyric acid methyl ester 
• 250226-93-8 (E)-4-((2R,4S,5R)-5-Hydroxy-2-phenyl-[1,3]dioxan-4-yl)-but-2-enoic acid methyl ester 

Downstream Products

• 439265-02-8 Trifluoro-methanesulfonic acid (2R,4aR,9aS)-2-phenyl-4a,8,9,9a-tetrahydro-4H-1,3,5-trioxa-benzocyclohepten-6-yl ester 
• 1548668-46-7 C₁₆H₂₀O₅ 
• 1548668-45-6 C₁₆H₂₀O₅ 
• 568572-02-1 {(2R,4aR,6S,7R,9aS)-6-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-3-(4-methoxy-benzyloxy)-oxepan-2-ylmethyl]-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-yloxy}-triethyl-silane 
• 568572-11-2 C₃₉H₅₇IO₈Si 
• 568572-03-2 (2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-((2R,4aR,6S,7R,9aS)-2-phenyl-7-triethylsilanyloxy-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl)-oxepan-3-ol 
• 568571-89-1 (2R,4aR,6S,7R,9aS)-6-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-3-(4-methoxy-benzyloxy)-oxepan-2-ylmethyl]-2-phenyl-hexahydro-1,3,5-trioxa-benzocyclohepten-7-ol 
• 568572-10-1 C₃₉H₅₈O₉Si 
• 568571-90-4 (2R,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-2-((2R,4aR,6S,7R,9aS)-2-phenyl-7-triethylsilanyloxy-hexahydro-1,3,5-trioxa-benzocyclohepten-6-ylmethyl)-oxepan-3-one 
• 568572-09-8 C₃₉H₅₆O₉Si 
• 568571-83-5 C₃₉H₅₆O₈Si 
• 850656-83-6 C₃₄H₄₈O₁₃S 
• 568571-88-0 (2R,4aR,9aS)-6-[(2R,3S,6R,7S)-6-Benzyloxy-7-benzyloxymethyl-3-(4-methoxy-benzyloxy)-oxepan-2-ylmethyl]-2-phenyl-4a,8,9,9a-tetrahydro-4H-1,3,5-trioxa-benzocycloheptene 
• 568572-00-9 C₃₃H₄₂O₉ 

Relevant academic research and scientific papers

Highly efficient synthesis of medium-sized lactones via oxidative lactonization: Concise total synthesis of isolaurepanf

A catalytic amount of TEMPO in the presence of PhI(OAc)2 effected oxidative lactonization of 1,6- and 1,7-diols, directly affording seven- and eight-membered lactones, respectively, in good yields. The Royal Society of Chemistry 2010.

A general strategy for the convergent synthesis of fused polycyclic ethers via B-alkyl Suzuki coupling: Synthesis of the ABCD ring fragment of ciguatoxins

A new method for convergent coupling of fused polycyclic ethers has been developed, which relies on B-alkyl Suzuki crosscoupling of lactone-derived enol triflates or phosphates. The strategy was successfully applied to a convergent synthesis of the ABCD r

A general method for convergent synthesis of polycyclic ethers based on Suzuki cross-coupling: Concise synthesis of the ABCD ring system of ciguatoxin

(matrix presented) A general method for convergent assembly of polyether structure has been developed based on palladium(0)-mediated Suzuki cross-coupling reaction of alkylboranes with cyclic ketene acetal phosphates. The present method allowed for coupli