250637-43-5Relevant articles and documents
Face selectivity in the reactions of Grignard reagents with 5-substituted-2-dicyanomethyIeneadamantanes
Kao, Kuo-Hsi,Siicu, Ren-Shyang,Clicn, Yuh-Shih,Lin, Wen-Wci,Liu, Ju-Tsung,Ching-FaYao
, p. 2383 - 2390 (1999)
Reactions of 5-substituted-2-dicyanomethyleneadamantanes (4-Z) with benzylmagnesium bromide (C6H5CH2MgBr) or alkylmagnesium halides (RMgX) generated the 1,4-addition (5-Z (R)) and/or the hydrogenation (5-Z (H)) products. A variety of substituen