25084-54-2Relevant academic research and scientific papers
Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 under iridium catalysis
Zheng, Sheng-Cai,Zhang, Min,Zhao, Xiao-Ming
, p. 7216 - 7221 (2014/06/23)
Enantioselective transformation of allyl carbonates into branched allyl carbamates by using amines and recycling CO2 in the presence of an Ir complex and K3PO4 was accomplished. This provided branched allyl carbamates in fair to excellent yields with up to 98:2 regioselectivity and 93% ee. The role of CO2 in this transformation is discussed as well.
Enantioselective domino reaction of CO2, amines and allyl chlorides under iridium catalysis: Formation of allyl carbamates
Zhang, Min,Zhao, Xiaoming,Zheng, Shengcai
supporting information, p. 4455 - 4458 (2014/04/17)
The enantioselective domino reaction between CO2 (1 atm), amines and linear allyl chlorides in the presence of an iridium complex, DABCO and toluene at 15 °C was realized, which gave branched allyl carbamates in acceptable to high yields with u
