25112-91-8

Upstream product

• 186581-53-3 diazomethane 
• 1193-55-1 2-methylcyclohexane-1,3-dione 
• 67-56-1 methanol 
• 676-88-0 dimethyl(methylthio)sulfonium tetrafluoroborate 
• 29829-22-9 S-methyldibenzothiophenium tetrafluoroborate 
• 70-25-7 N-Methyl-N'-nitro-N-nitrosoguanidine 
• 32774-63-3 3-hydroxy-2-methyl-cyclohex-2-enone 
• 149-73-5 trimethyl orthoformate 
• 504-02-9 1,3-cylohexanedione 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 73524-14-8 4-methyl-2-(2-methyl-3-oxo-1-cyclohexenylmethyl)-3-furoic acid 
• 132783-34-7 Benzoic acid 4-methoxy-3-methyl-2-oxo-cyclohex-3-enyl ester 
• 36887-92-0 3-amino-2-methylcyclohex-2-enone 
• 174910-90-8 3-methoxy-2,6,6-trimethylcyclohex-2-en-1-one 
• 219646-64-7 dimethyl 5-hydroxy-3-methoxy-4-methylphthalate 
• 132783-35-8 6-acetoxy-3-methoxy-2-methyl-2-cyclohexen-1-one 
• 944111-07-3 2-methyl-3-(4'-methylpent-4'-enyl)cyclohex-2-en-1-one 
• 944111-10-8 (+/-)-2-methyl-3-(4'-methylpent-4'-enyl)cyclohex-2-en-1-ol 
• 82929-62-2 3-ethoxyvinyl-2-methyl-2-cyclohexenone 
• 142436-77-9 (2R,3R)-2-methyl-3-deuteriocyclohexan-1-one 
• 142436-76-8 (-)-(2R,3S)-2-methyl-3-deuteriocyclohexan-1-one 
• 936226-24-3 3-methoxy-2-methyl-cyclohex-2-enone oxime 
• 219646-62-5 TMSOC₆H₅MeOMe 

Relevant academic research and scientific papers

Concise Construction of the ACDE Ring System of Calyciphylline A Type Alkaloids by a [5+2] Cycloaddition

A concise route for construction of the ACDE ring skeleton in calyciphylline A type alkaloids was developed using an intramolecular [5+2] cycloaddition reaction of an oxidopyrylium species bearing a tetrasubstituted olefin. Key to the success of this reaction was the combination of acid and base, which accelerated the construction of this skeleton containing a spiro ring and vicinal quaternary carbon centers. The resultant tricyclic ADE ring compound was converted to an ACDE ring model through C?H oxidation and an aza-Wittig reaction.

Synthesis of a series of promising isobenzofuranones for the treatment of acute mucositis caused by chemo- and radiotherapy

A small series of 3,5-dihydroxy-7-methoxy-3,6-dimethylshyisobenzofuran- 1(3H)-one analogues of the immunosuppressant, mycophenolate mofelite (MMF), has been identified during a screening campaign as possible mediators to prevent mucositis. Herein, we pres

Synthesis of novel antifungal phthalides produced by a wheat rhizosphere fungus

Two antifungal phthalides produced by a wheat rhizosphere fungus have been synthesized using the?Alder-Rickert reaction to construct their common isobenzofuranone core structure. The absolute configuration of one of the two phthalides has been determined

PROCESS FOR PREPARING SUBSTITUTED ANISIDINES

Disclosed is a process for preparing substituted anisidines of formula I starting from substituted cyclic hydroxy-ketones II via aromatization through a substituted oxime intermediate IV in which R is C1-C6 alkyl or halogen, and Alk is C1-C6 alkyl. The su

Microbiological synthesis of optically active (2R,3S)-2,3-deuteriocyclohexan-1-ones and (2R,3S)-2methyl-3-deuteriocyclohexan-1-one. Enantiospecific anti-addition of hydrogen to the double bond of cyclohex-2-en-1-ones

Addition of hydrogen of the double bond of cyclohexenones during microbiological reduction by Beauveria sulfurescens gives the trans product in high yield (90%) resulting from anti-addition to the si face on C-2 and the re face on C-3.

Carbon-carbon bond formation under aqueous reaction conditions using sulfonium and selenonium salt electrophiles

Methylation of relatively acidic (pK(a) 13) carbon nucleophiles occurs at neutral pH in aqueous media using suitably substituted methyl sulfonium and selenonium salt electrophiles.