25144-40-5

Usage

Chemical Class

Insect growth regulator

Function

Inhibits the synthesis of chitin in insects

Effect on Insects

Disruption of growth and development

Application

Used in agriculture to control insect pests

Target Pests

Caterpillars, beetles, and flies

Crop Usage

Cotton, fruits, and vegetables

Environmental Safety

Considered relatively safe for use in the environment

Mammalian Toxicity

Low toxicity to mammals

Precautions

Can cause skin and eye irritation

Hazardous Ingestion

May be harmful if swallowed

Handling

Handle with care to avoid irritation and ingestion

Upstream product

• 92291-63-9 1-<2-Chlorphenyl>-2-<4-chlorphenyl>-aethanol 
• 92291-61-7 1-<4-Chlorphenyl>-2-<2-chlorphenyl>-aethanol 
• 140-10-3 (E)-3-phenylacrylic acid 
• 89-98-5 2-chloro-benzaldehyde 
• 92152-98-2 2-(2-chlorophenyl)-1-(4-chlorophenyl)ethanone 
• 22568-07-6 1-chloro-2-(2-nitrovinyl)benzene 
• 106-47-8 4-chloro-aniline 
• 1615-02-7 3-(4-chlorophenyl)prop-2-enoic acid 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 

Downstream Products

• 93469-26-2 2,4-dichloro-bibenzyl 

Relevant academic research and scientific papers

Decarboxylative Arylation of α,β-Unsaturated Carboxylic Acids Using Aryl Triazenes by Copper/Ionic Liquid Combination in PEG-400

A practical method for the construction of stilbene derivatives has been developed via catalytic cross-coupling of cinnamic acids with aryl triazenes. The methodology offers high stereoselectivity and is endowed with broad substrate scope, high yield, and significant functional group tolerance.

Synthesis of stilbene derivatives via visible-light-induced cross-coupling of aryl diazonium salts with nitroalkenes using-NO2 as a leaving group

The straightforward visible-light-induced synthesis of stilbene compounds via the cross-coupling of nitroalkenes and diazonium tetrafluoroborates under transition-metal-free conditions is described. The protocol uses green LEDs as light sources and eosin Y as an organophotoredox catalyst. Broad substrate scope and exclusive selectivity for the (E)-configuration of stilbenes are observed. This protocol proceeds via a radical pathway, with nitroalkenes serving as the radical acceptor, and the nitro group is cleaved during the process.

OLEFIN SYNTHESIS VIA THE LITHIUM DERIVATIVES OF THE N,N,N',N'-TETRAMETHYLDIAMIDES OF ARYLMETHANEPHOSPHONIC ACIDS. 2. SYNTHESIS OF SOME (Z)-ORTHO AND PARA SUBSTITUTED STILBENES

The reaction of the lithium derivatives of N,N,N',N'-tetramethyldiamides of arylmethanophosphonic acids (1-Li) with ortho- and para-substituted benzaldehydes 2 is studied.Reaction conditions are found for erythro-stereoselective addition of 1 to 2 with high diastereomeric purity (95-99percent) of the rythro adducts 3, 4 (yields 35-72percent).By thermolysis of the adducts in neutral medium the corresponding (Z)-ortho and para-substituted silbenes 5, 6 are obtained.Some factors causing the predominant formation of the erythro adducts 3, 4, as well as the influence of the ortho-substituents on the equilibrium are discussed.