251645-83-7 Usage
Uses
Used in Organic Chemistry:
(1S,E)-(-)-Camphorquinone 3-oxime is used as a reagent in organic chemistry for the synthesis of different organic compounds, contributing to the development of new chemical entities and materials.
Used in Dental Applications:
In the dental industry, (1S,E)-(-)-Camphorquinone 3-oxime is used as a photoinitiator for the polymerization of dental resins. Its application facilitates the curing process, ensuring the proper hardening and setting of dental materials to achieve optimal dental restorations.
Used in Antimicrobial Development:
(1S,E)-(-)-Camphorquinone 3-oxime has been studied for its potential use in the development of antimicrobial agents. Its properties are being explored to create new compounds that can effectively combat microbial infections.
Used as a Chiral Auxiliary in Organic Synthesis:
Furthermore, (1S,E)-(-)-Camphorquinone 3-oxime serves as a chiral auxiliary in organic synthesis. This application is crucial for the production of enantiomerically pure compounds, which are essential in various pharmaceutical and chemical industries.
Check Digit Verification of cas no
The CAS Registry Mumber 251645-83-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,5,1,6,4 and 5 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 251645-83:
(8*2)+(7*5)+(6*1)+(5*6)+(4*4)+(3*5)+(2*8)+(1*3)=137
137 % 10 = 7
So 251645-83-7 is a valid CAS Registry Number.
InChI:InChI=1/C10H15NO2/c1-11-7-3-5-8(10(12)13-2)9(11)6-4-7/h5,7,9H,3-4,6H2,1-2H3
251645-83-7Relevant academic research and scientific papers
Chiral thiourea derivatives as organocatalyts in the enantioselective Morita- Baylis-Hillman reactions
Aydin, A. Ebru
, (2020/08/28)
Novel chiral bifunctional thiourea derivatives have been synthesised and successfully applied to the intermolecular Morita-Baylis-Hillman (MBH) reaction of an aromatic aldehyde with methyl vinyl ketone (MVK) and to the intramolecular MBH reaction of ω-for
Camphor-based Schiff base ligand SBAIB: An enantioselective catalyst for addition of phenylacetylene to aldehydes
Boobalan, Ramalingam,Chen, Chinpiao,Lee, Gene-Hsian
, p. 1625 - 1638 (2012/03/22)
A series of Schiff base ligands were synthesized from (1R)-camphor. Under the optimal conditions, (+)-SBAIB-a, 10 was found to be an excellent catalyst for the enantioselective addition of phenylacetylene to various aldehydes without utilizing either achiral additives or Ti(OiPr)4. This approach yielded (R)-propargylic alcohols in extremely high yields (up to 99%) and excellent enantioselectivities (up to 92%). The corresponding (S)-propargylic alcohols were synthesized in good to high enantioselectivities (up to 91%) and excellent yields (up to 99%) using (-)-SBAIB-a, 41.
A SYNTHON FOR CHIRAL GLYCOLATE ENOLATE (ROC-HCOOR'): A CAMPHOR-BASED OXAZOLINE
Kelly, T. Ross,Arvanitis, Argyrios
, p. 39 - 42 (2007/10/02)
Alkylations of the anion (7a) derived from a camphor-based oxazoline proceed in good yield.Hydrolysis affords the corresponding α-hydroxy acids in high ee.
