25172-54-7

Basic information

• Product Name: (E)-1-(2-hydroxy-5-methylphenyl)ethanone oxime
• CAS NO: 25172-54-7
• Molecular Weight: 165.192
• Mol File: 25172-54-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: (E)-1-(2-hydroxy-5-methylphenyl)ethanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(2-hydroxy-5-methylphenyl)ethanone oxime(25172-54-7)
• EPA Substance Registry System: (E)-1-(2-hydroxy-5-methylphenyl)ethanone oxime(25172-54-7)

Safety Data

• Hazardous Substances Data: 25172-54-7(Hazardous Substances Data)

Upstream product

• 108-95-2 phenol 
• 123-08-0 4-hydroxy-benzaldehyde 
• 106-44-5 p-cresol 
• 1450-72-2 5-methyl-2-hydroxyacetophenone 
• 79-24-3 Nitroethane 
• 1206606-64-5 C₁₃H₁₅NO₄ 

Downstream Products

• 6375-17-3 2-acetylamino-p-cresol 
• 6387-15-1 3-amino-2-hydroxy-5-methylbenzenesulfonic acid 
• 1285695-62-6 1-(2,4-dinitrophenyl)-4-(5-methyl-benzoxazol-2-yl)pyrazole 
• 1285695-58-0 1-phenyl-4-(5-methylbenzoxazol-2-yl)pyrazole 
• 201941-49-3 [Cu(S₂CN(CH₂C₆H₅)2)(OC₆H₃(CH₃)CCH₃(NOH))] 
• 76288-34-1 7-Methyl-4-phenyl-3a,10b-dihydro-4H-2,10-dioxa-10a-aza-cyclopenta[a]fluorene-1,3-dione 
• 76288-28-3 3-(4-methoxystyryl)-1,2-benzisoxazole 
• 76288-26-1 5-Methyl-3-((E)-styryl)-benzo[d]isoxazole 
• 53155-26-3 3,5-dimethyl-1,2-benzisoxazole 
• 1450-72-2 5-methyl-2-hydroxyacetophenone 
• 5676-58-4 2,5-dimethyl-1,3-benzoxazole 
• 75633-01-1 3,5-dimethyl-1,2-benzisoxazole 2-oxide 

Relevant articles and documents

Molecular dynamics of cis-1-(2-hydroxy-5-methylphenyl)ethanone oxime and N-(2-hydroxy-4-methylphenyl)acetamide in solution studied by NMR spectroscopy

The formation of hydrogen bonds and molecular dynamics for themolecules cis-1-(2-hydroxy-5-methylphenyl)ethanone oxime (I) and N-(2-hydroxy-4- methylphenyl)acetamide (II) have been investigated in solution using NMR. The results confirm the formation of O-H...O, O-H...N and O...H-N type inter- and intramolecular hydrogen bonds. Spin-lattice relaxation times (T1), activation energy of molecular dynamics and energy of intramolecular hydrogen bonds have been determined. Copyright

One-pot synthesis of benzoxazoles via the metal-free ortho-C-H functionalization of phenols with nitroalkanes

PPA-activated nitroalkanes are employed in the design of a one-pot cascade transformation involving metal-free and oxidant-free direct ortho-C-H functionalization, followed by Beckman rearrangement and intramolecular cyclocondensation to produce benzoxazoles and benzobisoxazoles directly from easily available phenols.

Synthesis of 1,2-benzisoxazole 2-oxides

(Chemical Equation Presented) A series of 2-hydroxyaryl ketoximes were converted to the corresponding 1,2- benzisoxazole 2-oxides by treatment with iodobenzene diacetate (in acetic acid or methanol) or N-chlorosuccinimide in water. Both methods gave moderate to excellent yields for a variety of substituted oximes under mild conditions within short reaction times. The latter method has the advantages of an aqueous solvent and lack of halogenated organic by-products. Copyright Taylor & Francis Group, LLC.