252264-47-4Relevant academic research and scientific papers
Efficient transfer hydrogenation of alkynes and alkenes with methanol catalysed by hydrido(methoxo)iridium(III) complexes
Tani, Kazuhide,Iseki, Aika,Yamagata, Tsuneaki
, p. 1821 - 1822 (1999)
Hydrido(methoxo)iridium(III) complexes, [{Ir(H)(diphosphine)}2(μ-OMe)2(μ-Cl)]+Cl- [diphosphine = (R)-BINAP 2a or 2,2'-bis(diphenylphosphino)-1,1'-biphenyl (BPBP) 2b] catalysed transfer hydrogenation of alkynes with methanol to give trans-alkenes selectively; plausible reaction pathways are also proposed.
