25236-81-1Relevant academic research and scientific papers
ACTIVATION OF POLYHALOALKANES BY PALLADIUM CATALYST. PREPARATION OF γ-TRICHLORO ESTERS BY COADDITION. REACTION OF CARBON TETRACHLORIDE AND CARBON MONOXIDE TO OLEFINS
Tsuji, Jiro,Sato, Koji,Nagashima, Hideo
, p. 893 - 896 (1982)
Pd(OAc)2 combined with PPh3 catalyzed the coaddition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates.The best yields were obtained when the reaction was carried out in the presence of K2CO3 at low temperature.
PALLADIUM-CATALYZED ADDITION REACTION OF OLEFINS, CARBON TETRACHLORIDE AND CARBON MONOXIDE IN ALCOHOLS TO GIVE 2-ALKYL-4,4,4-TRICHLOROBUTANOATES
Tsuji, Jiro,Sato, Koji,Nagashima, Hideo
, p. 5003 - 5006 (2007/10/02)
Pd(OAc)2 combined with PPh3 is good catalyst for the addition reaction of CCl4 and CO to olefins in ethanol to afford ethyl 2-alkyl-4,4,4-trichlorobutanoates.The esters were obtained in satisfactory yields when the reaction was carried out at 50 deg C in
