Octanoic acid, 2-(2,2,2-trichloroethyl)-, ethyl ester

Base Information

• Chemical Name: Octanoic acid, 2-(2,2,2-trichloroethyl)-, ethyl ester
• CAS No.: 25236-81-1
• Molecular Formula: C12H21Cl3O2
• Mol file: 25236-81-1.mol

Synonyms:

Chemical Property of Octanoic acid, 2-(2,2,2-trichloroethyl)-, ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Octanoic acid, 2-(2,2,2-trichloroethyl)-, ethyl ester

There total 2 articles about Octanoic acid, 2-(2,2,2-trichloroethyl)-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

tetrachloromethane (56-23-5) + ethanol (64-17-5) + oct-1-ene (111-66-0,25068-25-1) + carbon monoxide (201230-82-2) → 1,1,1,3-tetrachlorononane (1070-27-5) + ethyl 2-hexyl-4,4,4-trichlorobutanoate (25236-81-1)

Guidance literature:

With potassium carbonate; palladium diacetate; triphenylphosphine; at 50 ℃; for 24h; under 15200 Torr;

DOI:10.1016/S0040-4020(01)96745-6

Reference yield: 39.0%

tetrachloromethane (56-23-5) + oct-1-ene (111-66-0,25068-25-1) → 1,1,1,3-tetrachlorononane (1070-27-5) + ethyl 2-hexyl-4,4,4-trichlorobutanoate (25236-81-1)

Guidance literature:

With palladium diacetate; carbon monoxide; potassium carbonate; triphenylphosphine; In ethanol; at 50 ℃; for 24h; under 15200 Torr;

DOI:10.1016/S0040-4039(00)86976-2

Reference yield:

ethyl 2-hexyl-4,4,4-trichlorobutanoate (25236-81-1) → 2-hexylsuccinic acid (5702-91-0)

Guidance literature:

With sulfuric acid;

DOI:10.1021/jo00834a029

upstream raw materials:

tetrachloromethane

ethanol

oct-1-ene

carbon monoxide

Downstream raw materials:

2-hexylsuccinic acid