25284-41-7Relevant academic research and scientific papers
Rhenium-mediated dehydrogenative silylation and highly regioselective hydrosilylation of nitrile substituted olefins
Dong, Hailin,Jiang, Yanfeng,Berke, Heinz
, p. 17 - 22 (2014)
The rhenium (I) complex [Re(CH3CN)3Br 2(NO)] catalyzes the homogeneous hydrosilylation of a variety of substituted acrylonitriles, which were converted into the corresponding silyl-substituted alkanes with high regioselectivity of up to 94%. The products were analyzed by 1H NMR and GC-MS. A rhenium specific mechanism is proposed for the hydrosilylation of olefins.
