Journal of Organometallic Chemistry p. 17 - 22 (2014)
Update date:2022-08-05
Topics:
Dong, Hailin
Jiang, Yanfeng
Berke, Heinz
The rhenium (I) complex [Re(CH3CN)3Br 2(NO)] catalyzes the homogeneous hydrosilylation of a variety of substituted acrylonitriles, which were converted into the corresponding silyl-substituted alkanes with high regioselectivity of up to 94%. The products were analyzed by 1H NMR and GC-MS. A rhenium specific mechanism is proposed for the hydrosilylation of olefins.
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