252961-65-2

Upstream product

• 132610-89-0 (-)-(R)-2-methyl-5-isopropenyl-3-phenylcyclohex-2-en-1-one 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 145490-09-1 2-phenylcarveol 

Downstream Products

• 252961-66-3 (1S,2R,4S,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 252961-57-2 (1S,2S,4S,6S)-2-Benzyloxy-4-isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptane 
• 252961-61-8 (1S,2R,4S,6S)-2-Benzyloxy-4-isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptane 
• 252961-67-4 (1S,2S,4S,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 

Relevant academic research and scientific papers

Unusual stereochemical course of epoxide rearrangement in a carvone-derived series

Carvone-derived 2,3-epoxy alcohol derivatives rearrange with stereoselective formation of ring-contracted ketones. In contrast to previously described similar processes, the stereochemical result seems to be independent of epoxide configuration.