145490-09-1

Upstream product

• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 108-86-1 bromobenzene 

Downstream Products

• 1206544-23-1 2-(5-isopropenyl-2-methyl-3-phenylcyclohex-2-enyl)-5-methylfuran 
• 132610-94-7 (-)-(5R)-5-<(S)-1-bromo-2-methoxyprop-2-yl>-2-methyl-3-phenylcyclohex-2-en-1-one 
• 132610-95-8 (-)-(5R)-5-<(R)-1-bromo-2-methoxyprop-2-yl>-2-methyl-3-phenylcyclohex-2-en-1-one 
• 252961-57-2 (1S,2S,4S,6S)-2-Benzyloxy-4-isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptane 
• 252961-61-8 (1S,2R,4S,6S)-2-Benzyloxy-4-isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptane 
• 252961-67-4 (1S,2S,4S,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 252961-66-3 (1S,2R,4S,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 252961-69-6 (1S,5R)-5-Isopropenyl-2-methyl-3-phenyl-cyclohex-2-enol 
• 252961-68-5 (1R,5R)-5-Isopropenyl-2-methyl-3-phenyl-cyclohex-2-enol 
• 252961-65-2 (1R,4R,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-one 
• 132610-89-0 (-)-(R)-2-methyl-5-isopropenyl-3-phenylcyclohex-2-en-1-one 

Relevant academic research and scientific papers

Radical cyclisation strategies to bridged systems. Regioselective construction of chiral bicyclo [2.2.2] and [3.2.1] octanes via 6-exo trig and 5-exo trig radical cyclisation reactions

Radical cyclisation reaction of the bromoenones 6 and 7, obtained from (R)-phenyl carvone 3, gave a mixture of bicyclo [2.2.2] and [3.2.1] octanones via competitive 6-exo trig and 5-exo trig modes. On the other hand, radical cyclisation reaction of the al

Iodine, a Mild Reagent for the Aromatization of Terpenoids

Efficient procedures based on the use of iodine for the aromatization of a series of terpenoids possessing diene and homoallylic or allylic alcohol functionalities are described. Different examples are reported as a proof-of-concept study. Furthermore, iodine also proved to mediate the dehydrogenation of testosterone.

Boronic acid catalyzed Friedel-Crafts reactions of allylic alcohols with electron-rich arenes and heteroarenes

(Chemical Equation Presented) Pentafluorophenylboronic acid catalyzes the regioselective coupling of structurally diverse allylic alcohols with a variety of electron-rich aromatic and heteroaromatic substrates under ambient conditions. The commercially av

Unusual stereochemical course of epoxide rearrangement in a carvone-derived series

Carvone-derived 2,3-epoxy alcohol derivatives rearrange with stereoselective formation of ring-contracted ketones. In contrast to previously described similar processes, the stereochemical result seems to be independent of epoxide configuration.