132610-89-0

Upstream product

• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 100-58-3 phenylmagnesium bromide 
• 145490-09-1 2-phenylcarveol 

Downstream Products

• 132610-94-7 (R)-5-(2-Bromo-1-methoxy-1-methyl-ethyl)-2-methyl-3-phenyl-cyclohex-2-enone 
• 252961-65-2 (1R,4R,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-one 
• 252961-68-5 (1R,5R)-5-Isopropenyl-2-methyl-3-phenyl-cyclohex-2-enol 
• 132696-81-2 (-)-(1S,4S,8R)-1,8-Dimethyl-8-methoxy-6-phenylbicyclo<2.2.2>oct-5-en-2-one 
• 791854-77-8 (1S,3S,4R,5R)-5-methoxy-1,5-dimethyl-7-phenyl-3-propylbicyclo[2.2.2]oct-7-en-2-one 
• 791854-76-7 (1S,3S,4R,5R)-3-allyl-5-methoxy-1,5-dimethyl-7-phenylbicyclo[2.2.2]oct-7-en-2-one 
• 791854-78-9 (1S,3S,4R,5R)-3-(but-3-enyl)-5-methoxy-1,5-dimethyl-7-phenylbicyclo[2.2.2]oct-7-en-2-one 
• 791854-75-6 (1S,3S,4R,5R)-3-benzyl-5-methoxy-1,5-dimethyl-7-phenylbicyclo[2.2.2]oct-7-en-2-one 
• 791854-87-0 (1S,4R,8R)-3-allyl-8-methoxy-1,8-dimethyl-6-phenylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 
• 791854-88-1 (1S,4R,8R)-8-methoxy-1,8-dimethyl-6-phenyl-3-propylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 
• 791854-89-2 (1S,4R,8R)-3-(but-3-enyl)-8-methoxy-1,8-dimethyl-6-phenylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 
• 791855-01-1 (1S,4R,8R)-3-benzyl-8-methoxy-1,8-dimethyl-6-phenylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 
• 132611-04-2 (1S,4S)-1,8-Dimethyl-8-methoxy-6-phenylbicyclo<2.2.2>oct-5-en-2-one 
• 132610-76-5 4-Bromo-1,5-dimethyl-7-phenyl-bicyclo[3.2.1]oct-6-en-2-one 

Relevant academic research and scientific papers

Chiral [2.2.2] dienes as ligands for Rh(I) in conjugate additions of boronic acids to a wide range of acceptors

We document a series of investigations that led to new substituted [2.2.2]-diene ligands which display high selectivity in Rh(I)-catalyzed conjugate addition reactions to substrates not previously examined with diene ligands. Moreover, we disclose an unexpected, interesting effect that results from the introduction of a third C=C onto the ligand scaffold (cf. 1).

Unusual stereochemical course of epoxide rearrangement in a carvone-derived series

Carvone-derived 2,3-epoxy alcohol derivatives rearrange with stereoselective formation of ring-contracted ketones. In contrast to previously described similar processes, the stereochemical result seems to be independent of epoxide configuration.

Radical cyclisation strategies to bridged systems. Regioselective construction of chiral bicyclo [2.2.2] and [3.2.1] octanes via 6-exo trig and 5-exo trig radical cyclisation reactions

Radical cyclisation reaction of the bromoenones 6 and 7, obtained from (R)-phenyl carvone 3, gave a mixture of bicyclo [2.2.2] and [3.2.1] octanones via competitive 6-exo trig and 5-exo trig modes. On the other hand, radical cyclisation reaction of the al

Cyclopropanes via an Efficient 3-Exo Trig Radical Cyclisation Reaction

The first examples of an exclusive formation of a cyclopropane via the 3-exo trig radical cyclisation of homoallyl bromides 13 and 14 are reported.