132610-89-0

Basic information

• Product Name: 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-3-phenyl-, (5R)-
• CAS NO: 132610-89-0
• Molecular Formula: C16H18O
• Molecular Weight: 226.318
• Mol File: 132610-89-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-3-phenyl-, (5R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-3-phenyl-, (5R)-(132610-89-0)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 2-methyl-5-(1-methylethenyl)-3-phenyl-, (5R)-(132610-89-0)

Safety Data

• Hazardous Substances Data: 132610-89-0(Hazardous Substances Data)

Upstream product

• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 100-58-3 phenylmagnesium bromide 
• 145490-09-1 2-phenylcarveol 

Downstream Products

• 132610-94-7 (R)-5-(2-Bromo-1-methoxy-1-methyl-ethyl)-2-methyl-3-phenyl-cyclohex-2-enone 
• 252961-65-2 (1R,4R,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-one 
• 252961-68-5 (1R,5R)-5-Isopropenyl-2-methyl-3-phenyl-cyclohex-2-enol 
• 132611-04-2 (1S,4S)-1,8-Dimethyl-8-methoxy-6-phenylbicyclo<2.2.2>oct-5-en-2-one 
• 132610-76-5 4-Bromo-1,5-dimethyl-7-phenyl-bicyclo[3.2.1]oct-6-en-2-one 
• 132610-75-4 (S)-8-Bromo-1,8-dimethyl-6-phenyl-bicyclo[2.2.2]oct-5-en-2-one 
• 252961-57-2 (1S,2S,4S,6S)-2-Benzyloxy-4-isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptane 
• 252961-61-8 (1S,2R,4S,6S)-2-Benzyloxy-4-isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptane 
• 252961-67-4 (1S,2S,4S,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 252961-66-3 (1S,2R,4S,6S)-4-Isopropenyl-1-methyl-6-phenyl-7-oxa-bicyclo[4.1.0]heptan-2-ol 
• 252961-69-6 (1S,5R)-5-Isopropenyl-2-methyl-3-phenyl-cyclohex-2-enol 
• 791855-01-1 (1S,4R,8R)-3-benzyl-8-methoxy-1,8-dimethyl-6-phenylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 
• 791854-89-2 (1S,4R,8R)-3-(but-3-enyl)-8-methoxy-1,8-dimethyl-6-phenylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 
• 791854-88-1 (1S,4R,8R)-8-methoxy-1,8-dimethyl-6-phenyl-3-propylbicyclo[2.2.2]octa-2,5-dien-2-yl trifluoromethanesulfonate 

Relevant articles and documents

Chiral [2.2.2] dienes as ligands for Rh(I) in conjugate additions of boronic acids to a wide range of acceptors

We document a series of investigations that led to new substituted [2.2.2]-diene ligands which display high selectivity in Rh(I)-catalyzed conjugate addition reactions to substrates not previously examined with diene ligands. Moreover, we disclose an unexpected, interesting effect that results from the introduction of a third C=C onto the ligand scaffold (cf. 1).

Radical cyclisation strategies to bridged systems. Regioselective construction of chiral bicyclo [2.2.2] and [3.2.1] octanes via 6-exo trig and 5-exo trig radical cyclisation reactions

Radical cyclisation reaction of the bromoenones 6 and 7, obtained from (R)-phenyl carvone 3, gave a mixture of bicyclo [2.2.2] and [3.2.1] octanones via competitive 6-exo trig and 5-exo trig modes. On the other hand, radical cyclisation reaction of the al