253143-37-2Relevant academic research and scientific papers
Clemmensen Reduction. XI. Fragmentation Reactions of Some 3-Acetylcycloalkanones
Bailey, Karen E.,Davis, Brian R.
, p. 1827 - 1834 (2007/10/03)
Clemmensen reduction of a series of 3-acetylcycloalkanones yields, as the major product, an acyclic unsaturated ketone, the product of fragmentation.Some normal carbonyl-methylene reduction also occurs.A mechanistic rationale for the fragmentation is advanced.
Stereochemical Investigations of Samarium(II) Iodide-Promoted 5-Exo and 6-Exo Ketyl-Olefin Radical Cyclization Reactions
Molander, Gary A.,McKie, Jeffrey A.
, p. 872 - 882 (2007/10/02)
Samarium(II) iodide (SmI2)-promoted ketyl cyclizations of several substituted, unsaturated ketones, providing various cyclpentyl and cyclohexyl systems, have been investigated.The resulting experiments provide stereochemical insight into these reactions and in addition outline the synthetic potential of these 5-exo and 6-exo radical cyclization processes.
